(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Base Information

Chemical Name:(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
CAS No.:144301-64-4
Molecular Formula:C₃₂H₃₆O₃SSi
Molecular Weight:528.788
Hs Code.:

Synonyms:(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Chemical Property:

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Technology Process of (1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

There total 3 articles about (1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 108-98-5
thiophenol

: (2R,3S,4S)-3,4-epoxy-4-(trimethylsilyl)-1-O-(triphenylmethyl)butane-1,2-diol

: 144301-64-4
(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Guidance literature:: With silica gel; for 24h;
DOI:10.1021/jo00050a041

Reference yield:

: 144242-28-4
(E)-1-O-(triphenylmethyl)-2-O,4-bis(trimethylsilyl)but-3-ene

: 144301-64-4
(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Guidance literature:: Multi-step reaction with 3 steps

1: 47 percent / 70 percent HClO₄ / toluene; methanol / 0.02 h

2: 13 percent / tetrabutyl hydroperoxide, VO(acac)2 / toluene / 2 h

3: 91 percent / silica gel / 24 h

With perchloric acid; bis(acetylacetonate)oxovanadium; tetrabutyl hydroperoxide; silica gel; In methanol; toluene;
DOI:10.1021/jo00050a041

Reference yield:

: 144301-58-6
(2S)-(E)-4-(trimethylsilyl)-1-O-(triphenylmethyl)but-3-ene-1,2-diol

: 144301-64-4
(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol

Guidance literature:: Multi-step reaction with 2 steps

1: 13 percent / tetrabutyl hydroperoxide, VO(acac)2 / toluene / 2 h

2: 91 percent / silica gel / 24 h

With bis(acetylacetonate)oxovanadium; tetrabutyl hydroperoxide; silica gel; In toluene;
DOI:10.1021/jo00050a041