morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

Base Information

Chemical Name:morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone
CAS No.:75209-56-2
Molecular Formula:C₁₈H₂₅NO₂
Molecular Weight:287.402
Hs Code.:

Synonyms:morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

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Technology Process of morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

There total 7 articles about morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.8%

: 110-91-8,99108-56-2
morpholine

: 35027-80-6
2-(m-methoxyphenyl)-cycloheptanone

: 75209-56-2
morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

Guidance literature:: With titanium tetrachloride; In benzene; 1.) room temp., overnight, 2.) 75-80 deg C, 8 h;
DOI:10.1248/cpb.28.1022

Reference yield:

: 2398-37-0
3-methoxyphenyl bromide

: 75209-56-2
morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Mg / 1.) THF, 2.) THF, room temp., 30 min, 50-55 deg C, 1 h

2: oxalic acid / toluene / 16 h / Heating

3: 1.) NaBH₄, BF₃*Et₂O, 2.) 10percent NaOH, 30percent H₂O₂ / 1.) THF, room temp., 15 h, 2.) THF, H₂O, room temp., 1 h

4: 33.6 percent / Na₂Cr₂O₇*2H₂O, conc. H₂SO₄ / diethyl ether; H₂O / 2 h / 5 - 13 °C

5: 75.8 percent / TiCl₄ / benzene / 1.) room temp., overnight, 2.) 75-80 deg C, 8 h

With sodium hydroxide; sodium tetrahydroborate; sodium dichromate; sulfuric acid; boron trifluoride diethyl etherate; dihydrogen peroxide; oxalic acid; titanium tetrachloride; magnesium; In diethyl ether; water; toluene; benzene;
DOI:10.1248/cpb.28.1022

Reference yield:

: 2082-28-2
1-(m-methoxyphenyl)cycloheptanol

: 75209-56-2
morpholine enamine of 2-(m-methoxyphenyl)cycloheptanone

Guidance literature:: Multi-step reaction with 4 steps

1: oxalic acid / toluene / 16 h / Heating

2: 1.) NaBH₄, BF₃*Et₂O, 2.) 10percent NaOH, 30percent H₂O₂ / 1.) THF, room temp., 15 h, 2.) THF, H₂O, room temp., 1 h

3: 33.6 percent / Na₂Cr₂O₇*2H₂O, conc. H₂SO₄ / diethyl ether; H₂O / 2 h / 5 - 13 °C

4: 75.8 percent / TiCl₄ / benzene / 1.) room temp., overnight, 2.) 75-80 deg C, 8 h

With sodium hydroxide; sodium tetrahydroborate; sodium dichromate; sulfuric acid; boron trifluoride diethyl etherate; dihydrogen peroxide; oxalic acid; titanium tetrachloride; In diethyl ether; water; toluene; benzene;
DOI:10.1248/cpb.28.1022