Bis(ethylenediamine)platinum(II) chloride

Base Information

• Chemical Name: Bis(ethylenediamine)platinum(II) chloride
• CAS No.: 21430-85-3
• Molecular Formula: C₄H₁₆Cl₂N₄Pt
• Molecular Weight: 386.184
• European Community (EC) Number: 621-918-3
• Mol file: 21430-85-3.mol

Synonyms:Bis(ethylenediamine)platinum(II) chloride;21430-85-3;Dichlorobis(ethylenediamine)platinum(II);MFCD00009881;SCHEMBL2531495;AKOS025310728;E81058;CIS-DICHLOROBIS(ETHYLENEDIAMINE)PLATINUM(II)

Chemical Property of Bis(ethylenediamine)platinum(II) chloride

Chemical Property:

• Vapor Pressure: 15.8mmHg at 25°C
• Melting Point: 300°C (dec.)
• Boiling Point: 119.7 °C at 760 mmHg
• Flash Point: 33.9 °C
• PSA: 104.08000
• LogP: -5.38570
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 385.039996
• Heavy Atom Count: 11
• Complexity: 8.8

Purity/Quality:

97% ^*data from raw suppliers

Bis(ethylenediamine)platinum(II) chloride, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CN)N.C(CN)N.Cl[Pt]Cl

Technology Process of Bis(ethylenediamine)platinum(II) chloride

There total 2 articles about Bis(ethylenediamine)platinum(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Pt(ethane-1,2-diamine)2]Cl2 → [Pt(en)2Cl2](2+) (19184-32-8,21430-85-3,29646-65-9,744136-56-9,747346-40-3)

Guidance literature:

With hexachloroiridate(IV); In water; byproducts: IrCl6(3-); the rections were carried out in H2O at pH=3.0 using NaClO4 to adjust the ionic strength at 20, 30, 40°C (presence of chloride);; monitored spectrophotometrically;; Kinetics;

Reference yield:

bis(1,2-diamino-ethane)-platinum(II) (2+) (19184-30-6) + potassium trans-dichlorotetracyanoplatinate(IV) → {Pten2Cl2}(2+) (19184-32-8,747346-40-3,29646-65-9,21430-85-3,744136-56-9) + trans-dichlorotetracyanoplatinate(IV)(2-)

Guidance literature:

In not given; excess of Pt(II)-complex, 25°C, in presence of varying excess of Cl(1-), I=1.00 M (NaClO4); not isolated, reaction followed by stopped-flow UV/VIS spectroscopy; Kinetics;

DOI:10.1016/S0020-1693(98)00199-6

Reference yield:

tris(2,2'-bipyridine)osmium(II) (23648-06-8,24191-05-7,174291-50-0) + {Pten2Cl2}(2+) (19184-32-8,747346-40-3,29646-65-9,21430-85-3,744136-56-9) → tris(2,2'-bipyridine)osmium(III)(3+) (30032-51-0) + {Pt(III)(ethylenediamine)2Cl2}(1+)

Guidance literature:

Kinetics;

DOI:10.1007/BF01373409

upstream raw materials:

bis(1,2-diamino-ethane)-platinum(II) ⁽²⁺⁾

Downstream raw materials:

tris(2,2'-bipyridine)osmium(III)⁽³⁺⁾

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