1-allyloxy-2-iodo-1-phenylsilacyclopentane

Base Information

• Chemical Name: 1-allyloxy-2-iodo-1-phenylsilacyclopentane
• CAS No.: 145782-46-3
• Molecular Formula: C₁₃H₁₇IOSi
• Molecular Weight: 344.267
• Mol file: 145782-46-3.mol

Synonyms:1-allyloxy-2-iodo-1-phenylsilacyclopentane

Chemical Property of 1-allyloxy-2-iodo-1-phenylsilacyclopentane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-allyloxy-2-iodo-1-phenylsilacyclopentane

There total 1 articles about 1-allyloxy-2-iodo-1-phenylsilacyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

diiodomethane (75-11-6) + 1-allyloxy-1-phenylsilacyclobutane (145782-61-2) → 1-allyloxy-2-iodo-1-phenylsilacyclopentane (145782-46-3)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h;

DOI:10.1246/bcsj.68.625

Reference yield:

1-allyloxy-2-iodo-1-phenylsilacyclopentane (145782-46-3) → (3aS,7S)-3-Iodomethyl-7-phenyl-hexahydro-silolo[1,2-b][1,2]oxasilole

Guidance literature:

With triethyl borane; tri-n-butyl-tin hydride; 1.) hexane, 25 deg C, 24 h, 2.) hexane, RT, 3 h;

DOI:10.1246/bcsj.68.625

upstream raw materials:

diiodomethane

1-allyloxy-1-phenylsilacyclobutane