Bis(tri-tert-butylphosphine)palladium(0)

Base Information

Chemical Name:Bis(tri-tert-butylphosphine)palladium(0)
CAS No.:53199-31-8
Molecular Formula:C24H54P2Pd
Molecular Weight:511.06
Hs Code.:28439000
European Community (EC) Number:640-284-9
DSSTox Substance ID:DTXSID80370359
Mol file:53199-31-8.mol

Synonyms:53199-31-8;Bis(tri-tert-butylphosphine)palladium(0);BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM;Bis(tri-t-butylphosphine)palladium(0);palladium;tritert-butylphosphane;bis(tri-tert-butylphosphane) palladium;Palladium, bis[tris(1,1-dimethylethyl)phosphine]-;pd(p(tbu)3)2;BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM;MFCD03094580;SCHEMBL43560;DTXSID80370359;AMY11805;BCP12194;STR08646;AC-953;AKOS015903145;bis(tri-tert-butylphosphine)-palladium;Bis[tris(tert-butyl)phosphine]palladium;PB42990;SC10403;Bis(tri-t-butylphosphine)palladium (0);B3161;FT-0650424;I10265;A829438

Suppliers and Price of Bis(tri-tert-butylphosphine)palladium(0)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Bis(tri-tert-butylphosphine)palladium(0)
1g
$ 250.00

TCI Chemical
Bis(tri-tert-butylphosphine)palladium(0) >98.0%(T)
1g
$ 222.00

TCI Chemical
Bis(tri-tert-butylphosphine)palladium(0) >98.0%(T)
250mg
$ 71.00

Strem Chemicals
Bis(tri-t-butylphosphine)palladium(0), 98%
25g
$ 3682.00

Strem Chemicals
Bis(tri-t-butylphosphine)palladium(0), 98%
5g
$ 982.00

Strem Chemicals
Bis(tri-t-butylphosphine)palladium(0), 98%
250mg
$ 96.00

Strem Chemicals
Bis(tri-t-butylphosphine)palladium(0), 98%
1g
$ 262.00

Sigma-Aldrich
Bis(tri-tert-butylphosphine)palladium(0)
1g
$ 254.00

Sigma-Aldrich
Bis(tri-tert-butylphosphine)palladium(0)
250mg
$ 104.00

Matrix Scientific
Bis[tris(tert-butyl)phosphine]palladium >95%
5g
$ 395.00

Total 122 raw suppliers

Chemical Property of Bis(tri-tert-butylphosphine)palladium(0)

Chemical Property:

Appearance/Colour:Off white crystalline solid
Vapor Pressure:0.105mmHg at 25°C
Melting Point:>300 °C
Boiling Point:229.4 °C at 760 mmHg
Flash Point:94.6 °C
PSA：27.18000
LogP:9.72760
Storage Temp.:Freezer
Sensitive.:Light, Air & Moisture Sensitive
Water Solubility.:insoluble
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:510.27356
Heavy Atom Count:27
Complexity:128

Purity/Quality:

99% ^*data from raw suppliers

Bis(tri-tert-butylphosphine)palladium(0) ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pd]
Uses Catalyst for Suzuki coupling on a multisubstituted sp 3 -carbon (eq. 1) Catalyst for Stille coupling reaction of aryl chlorides 2 (eq. 2) Catalyst for Negishi coupling reaction 3 (eq. 3) Catalyst for Heck coupling to form tetrasubstituted olefins 4 (eq. 4) Catalyst for Buchwald-Hartwig amination of aryl halide 5 (eq. 5) Catalyst for carbonylation of aryl halides with carbamoylsilanes 6 (eq. 6) t -Bu 3 P) 2 catalyst. Bis(tri-tert-butylphosphine)palladium(0) is used in Coupling reactions, Heck couplings. It acts as a palladium catalyst for reductive carbonylation.

Technology Process of Bis(tri-tert-butylphosphine)palladium(0)

There total 50 articles about Bis(tri-tert-butylphosphine)palladium(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: bis(η3-allyl-μ-chloropalladium(II))

: 13716-12-6
tri-tert-butyl phosphine

: 53199-31-8
bis(tri-t-butylphosphine)palladium⁽⁰⁾

Guidance literature:: In acetonitrile; for 18h; Inert atmosphere; Glovebox;
DOI:10.1002/chem.201500476

Reference yield: 83.0%

: 12145-47-0
cis-dibromo-(cyclooctadiene)palladium(II)

: 13716-12-6
tri-tert-butyl phosphine

: 53199-31-8
bis(tri-t-butylphosphine)palladium⁽⁰⁾

Guidance literature:: In methanol; toluene; at 20 ℃; for 2.66667h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;

Reference yield: 83.0%

: tris(dibenzylideneacetone)dipalladium ⁽⁰⁾

: 13716-12-6
tri-tert-butyl phosphine

: 53199-31-8
bis(tri-t-butylphosphine)palladium⁽⁰⁾

Guidance literature:: In N,N-dimethyl-formamide; under Ar; mixt. stirred for 3 h at room temp.; ppt. filtered; washed (DMF); dissolved (hexane); soln. filtered and concd.;
DOI:10.1021/ja003954y