(R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl

Base Information

• Chemical Name: (R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl
• CAS No.: 721944-89-4
• Molecular Formula: C₂₅H₂₀FeOS₂
• Molecular Weight: 456.412
• Mol file: 721944-89-4.mol

Synonyms:(R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl

Chemical Property of (R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl

There total 1 articles about (R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diethyl benzo[d][1,3]dithiol-2-yl-phosphonate (62217-21-4) + (R(Fc))-(α-p-methoxyphenyl)ferrocenecarboxaldehyde (344914-05-2,63397-85-3) → (R(Fc))-(α-p-methoxyphenyl)-1,3-benzodithiol-2-ylferrocenylvinyl (721944-89-4)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; under Ar; THF added to mixt. of Fe-complex and phosphonate in Schlenk tube, cooled to 0°C, soln. of t-BuOK in THF slowly added, mixt. warmed to room temp., stirred overnight; quenched with water at 0°C, extd. with CH2Cl2, extract dried overMgSO4, filtered, filtrate evapd., flash chromy. (silica gel, Et2O/CH2Cl 2 (1/1));

DOI:10.1039/b300397n

upstream raw materials:

diethyl benzo[d][1,3]dithiol-2-yl-phosphonate

(R(Fc))-(α-p-methoxyphenyl)ferrocenecarboxaldehyde