((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

Base Information

Chemical Name:((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene
CAS No.:213337-95-2
Molecular Formula:C₃₄H₃₄O₄
Molecular Weight:506.642
Hs Code.:

Synonyms:((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

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Chemical Property of ((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

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Technology Process of ((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

There total 10 articles about ((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 213337-91-8
(3aR,4S,5R,6R,6aS)-4,5,6-Tris-benzyloxy-3a-benzyloxymethyl-tetrahydro-cyclopenta[1,3]dioxole-2-thione

: 213337-95-2
((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

Guidance literature:: With triethyl phosphite; at 155 ℃; for 2h;
DOI:10.1021/jo980831b

Reference yield: 40.0%

: (2R,3S,4S,5R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-thiopyran 1,1-dioxide

: 213337-95-2
((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at -78 ℃;
DOI:10.1016/S0040-4039(00)02209-7

Reference yield:

: 4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9
2,3,4,6-Tetra-O-benzyl-D-glucopyranose

: 213337-95-2
((((1S,2R,3R)-4-((benzyloxy)methyl)cyclopent-4-ene-1,2,3-triyl)tris(oxy))tris(methylene))tribenzene

Guidance literature:: Multi-step reaction with 5 steps

1: 98 percent / NaBH₄ / ethanol; CH₂Cl₂ / 20 °C

2: (COCl)2; DMSO; Et₃N / tetrahydrofuran / 1.75 h / -65 - 20 °C

3: 3.54 g / SmI₂; t-BuOH / tetrahydrofuran / -50 - 20 °C

4: 45 percent / toluene / 4 h / 110 °C

5: 93 percent / (EtO)3P / 2 h / 155 °C

With sodium tetrahydroborate; samarium diiodide; oxalyl dichloride; dimethyl sulfoxide; triethylamine; tert-butyl alcohol; triethyl phosphite; In tetrahydrofuran; ethanol; dichloromethane; toluene; 1: Reduction / 2: Swern oxidation / 3: Cyclization / 4: Cyclization / 5: Elimination;
DOI:10.1021/jo980831b