2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

Base Information

Chemical Name:2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose
CAS No.:133473-13-9
Molecular Formula:C₃₁H₃₃NO₅
Molecular Weight:499.607
Hs Code.:

Synonyms:2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

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Chemical Property of 2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

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Technology Process of 2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

There total 5 articles about 2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 117462-55-2
methyl 2-azido-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannonate

: 133473-13-9
2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

Guidance literature:: Multi-step reaction with 4 steps

1: H₂ / 10percent Pd/C / ethyl acetate / 24 h / 760 Torr

2: Pb(NO₃)2, Et₃N / CH₂Cl₂ / 48 h / Ambient temperature

3: 94 percent / DIBAL / toluene / 0.5 h / -78 °C

4: 1) N-chlorosuccinimide, Me₂S, 2) NEt₃ / 1) toluene, -25 deg C, 5.5 h, 2) 20 min.

With N-chloro-succinimide; lead(II) nitrate; dimethylsulfide; hydrogen; diisobutylaluminium hydride; triethylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate; toluene;
DOI:10.1021/jo00011a047

Reference yield:

: 55135-66-5
9-bromo-9-phenyl-9H-fluorene

: 133473-13-9
2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

Guidance literature:: Multi-step reaction with 3 steps

1: Pb(NO₃)2, Et₃N / CH₂Cl₂ / 48 h / Ambient temperature

2: 94 percent / DIBAL / toluene / 0.5 h / -78 °C

3: 1) N-chlorosuccinimide, Me₂S, 2) NEt₃ / 1) toluene, -25 deg C, 5.5 h, 2) 20 min.

With N-chloro-succinimide; lead(II) nitrate; dimethylsulfide; diisobutylaluminium hydride; triethylamine; In dichloromethane; toluene;
DOI:10.1021/jo00011a047

Reference yield:

: 133473-08-2
methyl 3,4;5,6-di-O-isopropylidene-2-amino-2-deoxy-D-mannate

: 133473-13-9
2-<(9-phenylfluoren-9-yl)amino>-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose

Guidance literature:: Multi-step reaction with 3 steps

1: Pb(NO₃)2, Et₃N / CH₂Cl₂ / 48 h / Ambient temperature

2: 94 percent / DIBAL / toluene / 0.5 h / -78 °C

3: 1) N-chlorosuccinimide, Me₂S, 2) NEt₃ / 1) toluene, -25 deg C, 5.5 h, 2) 20 min.

With N-chloro-succinimide; lead(II) nitrate; dimethylsulfide; diisobutylaluminium hydride; triethylamine; In dichloromethane; toluene;
DOI:10.1021/jo00011a047