14-hydroxytetradecan-7-one

Base Information

Chemical Name:14-hydroxytetradecan-7-one
CAS No.:76190-93-7
Molecular Formula:C₁₄H₂₈O₂
Molecular Weight:228.375
Hs Code.:

Synonyms:14-hydroxytetradecan-7-one

Suppliers and Price of 14-hydroxytetradecan-7-one

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Chemical Property of 14-hydroxytetradecan-7-one

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 14-hydroxytetradecan-7-one

There total 1 articles about 14-hydroxytetradecan-7-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 629-11-8
1,6-hexanediol

: 111-13-7
hexyl-methyl-ketone

: 31335-17-8
7,16-docosanedione

: 4128-31-8,113301-48-7,4128-32-9
rac-octan-2-ol

: 76190-93-7
14-hydroxytetradecan-7-one

Guidance literature:: With potassium hydroxide; bis(1,5-cyclooctadiene)diiridium(I) dichloride; 1,7-Octadiene; triphenylphosphine; In 1,4-dioxane; at 100 ℃; for 15h; Inert atmosphere;
DOI:10.1246/bcsj.81.689

Reference yield:

: 76190-93-7
14-hydroxytetradecan-7-one

: 76183-01-2
1-{(4R,5S)-5-[(E)-9-(2-Hexyl-5,5-dimethyl-[1,3]dioxan-2-yl)-non-2-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-2-trityloxy-ethanone

Guidance literature:: Multi-step reaction with 8 steps

1: 97 percent / p-toluenesulfonic acid monohydrate / benzene / Heating; Dean Stark trap

2: 87 percent / triphenylphosphine, N-bromosuccinimide / dimethylformamide

3: 85 percent / trimethylorthophormate / acetonitrile / 14 h / 90 °C

4: 86 percent / 1.) 1.6 N n-BuLi / 1.) hexane, THF, 25 deg C, 10 min; 2.) THF, hexane, -70 deg C, 5 min

5: 95 percent / m-chloroperbenzoic acid / cyclohexane / 30 min, 5 deg C; 2.5 h, r.t.

6: 1.) 0.45 M lithium diphenylphosphide; 2.) methyl iodide / 1.) THF, 20 min, 25 deg C; 2.) 90 min, THF

7: 88 percent / tetra-n-butylammonium fluoride trihydrate / tetrahydrofuran / Heating

8: 87 percent / dimethyl sulfoxide, acetic anhydride / 18 h / Ambient temperature

With N-Bromosuccinimide; n-butyllithium; tetrabutyl ammonium fluoride; acetic anhydride; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium diphenylphosphide; methyl iodide; trimethyl orthoformate; toluene-4-sulfonic acid; In tetrahydrofuran; cyclohexane; N,N-dimethyl-formamide; acetonitrile; benzene;
DOI:10.1139/v81-044

Reference yield:

: 76190-93-7
14-hydroxytetradecan-7-one

: 76182-99-5
7-(5,5-dimethyl-2-n-hexyl-1-3-dioxan-2-yl)-n-heptyl-triphenylphosphonium bromide

Guidance literature:: Multi-step reaction with 3 steps

1: 97 percent / p-toluenesulfonic acid monohydrate / benzene / Heating; Dean Stark trap

2: 87 percent / triphenylphosphine, N-bromosuccinimide / dimethylformamide

3: 85 percent / trimethylorthophormate / acetonitrile / 14 h / 90 °C

With N-Bromosuccinimide; triphenylphosphine; trimethyl orthoformate; toluene-4-sulfonic acid; In N,N-dimethyl-formamide; acetonitrile; benzene;
DOI:10.1139/v81-044