bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide

Base Information

Chemical Name:bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide
CAS No.:112896-24-9
Molecular Formula:Br*C₂₂H₄₁BrNNiP₄
Molecular Weight:661.967
Hs Code.:

Synonyms:bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide

Suppliers and Price of bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide

There total 2 articles about bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 79351-76-1
Ni(CH₃HP(CH₂)3P(C₆H₅)(CH₂)3PHCH₃)Br₂

: 112896-24-9
bromo(4-diethylamino-1,7-dimethyl-11-phenyl-1,4,7,11-tetraphosphacyclotetradecane)nickel(II) bromide

Guidance literature:: With Et₂N-P(CH=CH₂)2; In dichloromethane; treatments of solns. of reagents (during 3 h), concn. (vacuum, 20°C); pptn. on addn. of Et2O, drying (vacuum, 20°C); elem. anal.;

Reference yield: 24.7%

: 79351-76-1
Ni(CH₃HP(CH₂)3P(C₆H₅)(CH₂)3PHCH₃)Br₂

: 63034-50-4
Diethylamino(divinyl)phosphine

: 142433-66-7,112896-24-9,142433-70-3,142433-71-4
NiBr((C₆H₅)P((CH₂)3P(CH₃)(CH₂)2)2PN(C₂H₅)2)⁽¹⁺⁾*Br^(1-) = C₂₂H₄₁Br₂NNiP₄

Guidance literature:: In dichloromethane; dropping of dild. solns. of org. compd. in CH2Cl2 and Ni-compd. in CH2Cl2 into CH2Cl2 (within 2-5 h); evapn., addn. of Et2O, filtration, drying (1E-3 mbar); elem. anal.;

Reference yield: 47.0%

: 142433-66-7,112896-24-9,142433-70-3,142433-71-4
NiBr((C₆H₅)P((CH₂)3P(CH₃)(CH₂)2)2PN(C₂H₅)2)⁽¹⁺⁾*Br^(1-) = C₂₂H₄₁Br₂NNiP₄

: 142433-77-0,142433-67-8,142433-78-1,142433-79-2
NiBr((C₆H₅)P((CH₂)3P(CH₃)(CH₂)2)2POH)⁽¹⁺⁾*Br^(1-) = C₁₈H₃₂Br₂ONiP₄

Guidance literature:: With HBr; In water; addn. of 62% HBr to an aq. soln. of the Ni compound; refluxing (20 h);; ppt. of one isomere; washing (H2O); drying (vac.); elem. anal.;;