(E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

Base Information

Chemical Name:(E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose
CAS No.:110921-00-1
Molecular Formula:C₂₂H₃₀O₇
Molecular Weight:406.476
Hs Code.:

Synonyms:(E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

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Chemical Property of (E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

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Technology Process of (E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

There total 7 articles about (E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 110921-05-6
methyl (E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranuronate

: 110921-00-1
(E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1016/0008-6215(86)84007-1

Reference yield: 70.5%

: 110920-99-5
(E)-(R)-4-Benzyloxy-4-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-yl)-but-2-enal

: 110921-00-1
(E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1016/0008-6215(86)84007-1

Reference yield:

: 4640-86-2
7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-hept-7-enopyranose

: 110921-00-1
(E)-6-O-benzyl-7,8-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-glycero-D-galacto-non-7-enopyranose

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) sodium hydride / 1.) tetrahydrofuran, 30 min, 2.) r.t.

2: 92 g / N-methylmorpholine N-oxide monohydrate, osmium tetraoxide / acetone; H₂O / 3 h / Ambient temperature

3: 2.93 g / sodium periodate / dioxane; H₂O / 2 h / Ambient temperature

4: 90 percent / benzene / 3 h / Heating

5: 70.5 percent / diisobutylaluminium hydride / CH₂Cl₂ / 2 h / 0 °C

With sodium periodate; osmium(VIII) oxide; sodium hydride; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; In 1,4-dioxane; dichloromethane; water; acetone; benzene;
DOI:10.1016/0008-6215(86)84007-1