Technology Process of C55H88O7SSi3
There total 13 articles about C55H88O7SSi3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 4 steps
1.1: 87 percent / N-methylmorpholine N-oxide; OsO4 / acetone; H2O / 20 °C
2.1: 97 percent / Pb(OAc)4 / toluene / 20 °C
3.1: 70 percent / n-butyllithium / tetrahydrofuran
4.1: n-butyllithium / tetrahydrofuran
4.2: tetrahydrofuran
With
lead(IV) acetate; osmium(VIII) oxide; n-butyllithium; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; water; acetone; toluene;
3.2: Colvin rearrangement;
DOI:10.1021/ol990884v
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 97 percent / Pb(OAc)4 / toluene / 20 °C
2.1: 70 percent / n-butyllithium / tetrahydrofuran
3.1: n-butyllithium / tetrahydrofuran
3.2: tetrahydrofuran
With
lead(IV) acetate; n-butyllithium;
In
tetrahydrofuran; toluene;
2.2: Colvin rearrangement;
DOI:10.1021/ol990884v
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 95 percent / lutidine / CH2Cl2 / 0 - 20 °C
2.1: 92 percent / NaIO4; RuCl3; phosphate buffer / acetonitrile / 20 °C / pH 8
3.1: Me2AlCl / CH2Cl2 / 0 - 20 °C
4.1: imidazole; 4-(dimethylamino)pyridine / dimethylformamide / 0 - 20 °C
5.1: 94 percent / acetic anhydride / 20 °C
6.1: n-butyllithium / tetrahydrofuran
6.2: tetrahydrofuran
With
1H-imidazole; dmap; ruthenium trichloride; sodium periodate; n-butyllithium; phosphate buffer; lutidine; dimethylaluminum chloride; acetic anhydride;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ol990884v