(c-C₆H₁₁)2SbLi

Base Information

• Chemical Name: (c-C₆H₁₁)2SbLi
• CAS No.: 1013-90-7
• Molecular Formula: C₁₂H₂₂LiSb
• Molecular Weight: 294.998
• Mol file: 1013-90-7.mol

Synonyms:(c-C₆H₁₁)2SbLi

Chemical Property of (c-C₆H₁₁)2SbLi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (c-C₆H₁₁)2SbLi

There total 2 articles about (c-C₆H₁₁)2SbLi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(c-C6H11)2SbH (1011-94-5) + phenyllithium (591-51-5) → (c-C6H11)2SbLi (1013-90-7)

Guidance literature:

In diethyl ether; in the absence of light at -35°C, pptg. on standing; washing with petroleum ether, drying;

Reference yield:

(C6H11)2SbCl (1013-89-4) → (c-C6H11)2SbLi (1013-90-7)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether

2: diethyl ether

With LiAlH₄; In diethyl ether;

Reference yield: 98.9%

(c-C6H11)2SbLi (1013-90-7) + 1,6-dichlorohexane (2163-00-0) → {(c-C6H11)2Sb}2(CH2)6 (1060-74-8)

Guidance literature:

In tetrahydrofuran; diethyl ether; drop by drop addn. of 1,6-dichlorohexane in THF over 30 min to a (c-C6H11)2SbLi soln. in ether at -45°C; mixt. treated with aq. NH4Cl, evapn. of the ether;

upstream raw materials:

(c-C₆H₁₁)2SbH

phenyllithium

(C₆H₁₁)2SbCl

Downstream raw materials:

{(c-C₆H₁₁)2Sb}2(CH₂)4

(c-C₆H₁₁)2Sb(CH₂)4Cl

{(c-C₆H₁₁)2Sb}2

ethene