(E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one

Base Information

• Chemical Name: (E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one
• CAS No.: 86471-74-1
• Molecular Formula: C₃₈H₅₆O₇S₂
• Molecular Weight: 688.99
• Mol file: 86471-74-1.mol

Synonyms:(E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one

Chemical Property of (E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one

There total 1 articles about (E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

12,12-Bis-benzenesulfonyl-dodecanoic acid 10-(3-vinyl-oxiranyl)-decyl ester (86471-73-0) → (E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one (86471-74-1)

Guidance literature:

poly-Pd; In tetrahydrofuran; for 3h; Heating;

DOI:10.1021/ja00356a051

Reference yield:

(E)-13,13-Bis-benzenesulfonyl-17-hydroxy-oxacycloheptacos-15-en-2-one (86471-74-1) → (13Z,15E)-13-Benzenesulfonyl-oxacycloheptacosa-13,15-diene-2,17-dione (86471-75-2)

Guidance literature:

With oxalyl dichloride; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; Yield given. Multistep reaction; 1.) CH₂Cl₂, 2.) CH₂Cl₂, room temperature;

DOI:10.1021/ja00356a051

upstream raw materials:

12,12-Bis-benzenesulfonyl-dodecanoic acid 10-(3-vinyl-oxiranyl)-decyl ester

Downstream raw materials:

(13Z,15E)-13-Benzenesulfonyl-oxacycloheptacosa-13,15-diene-2,17-dione