r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

Base Information

Chemical Name:r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide
CAS No.:79976-65-1
Molecular Formula:C₂₅H₂₅OPS
Molecular Weight:406.497
Hs Code.:

Synonyms:r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

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Chemical Property of r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

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Technology Process of r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

There total 3 articles about r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.4%

: 80009-42-3
r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-4-phosphorinanone 1-oxide

: 79976-65-1
r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

Guidance literature:: With water-d2; potassium carbonate; In 1,4-dioxane; for 36h; Heating;
DOI:10.1021/ja00415a031

Reference yield:

: 76173-30-3,80009-34-3,80009-41-2
r-1,cis-2(a),trans-6(e)-triphenyl-cis-3(e),5(e)-dimethyl-4-phosphorinanone

: 79976-65-1
r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / 0.5 h / 210 - 215 °C

2: 56.6 percent / m-chloroperbenzoic acid / acetone; diethyl ether / 1) 0 deg C, 0.5 h; 2) room temperature, 0.5 h

3: 89.4 percent / deuterium oxide, K₂CO₃ / dioxane / 36 h / Heating

With water-d2; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In 1,4-dioxane; diethyl ether; acetone;
DOI:10.1021/ja00415a031

Reference yield:

: 80009-41-2
r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-4-phosphorinanone

: 79976-65-1
r-1,trans-2(e),6(e)-triphenyl-cis-3(e),5(e)-dimethyl-3,5-dideuteriophosphorinan-4-one 1-sulfide

Guidance literature:: Multi-step reaction with 2 steps

1: 56.6 percent / m-chloroperbenzoic acid / acetone; diethyl ether / 1) 0 deg C, 0.5 h; 2) room temperature, 0.5 h

2: 89.4 percent / deuterium oxide, K₂CO₃ / dioxane / 36 h / Heating

With water-d2; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In 1,4-dioxane; diethyl ether; acetone;
DOI:10.1021/ja00415a031