[1-(2-Methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane

Base Information

• Chemical Name: [1-(2-Methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
• CAS No.: 145964-33-6
• Molecular Formula: C₃₃H₂₅OP
• Molecular Weight: 468.535
• European Community (EC) Number: 813-339-1
• Nikkaji Number: J1.599.104F,J1.572.176F,J529.567J
• Mol file: 145964-33-6.mol

Synonyms:145964-33-6;134484-36-9;(S)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine;(R)-MOP;(r)-(+)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl;145964-36-9;(R)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine;[1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;134484-37-0;(S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl;(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl;MFCD00269686;(2'-methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphane;(S)-2-DIPHENYLPHOSPHINO-2'-METHOXYL-1,1'-BINAPHTHYL;(S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(R)-(+)-2-DIPHENYLPHOSPHINO-2/'-METHOXY-1,1/'-BINAPHTHYL;(R)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl (R)-MOP;(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;161053-46-9;R-MOP;(S)-(-)-MOP;rmop;{2'-METHOXY-[1,1'-BINAPHTHALEN]-2-YL}DIPHENYLPHOSPHANE;(R)-(+)-MOP;(S)-2-(Diphenylphosphino)-2-methoxy-1,1-binaphthyl;SCHEMBL1606348;(S)-2-DIPHENYPHOSPHINO-2'-METHOXYL-1,1'-BINAPHTHYL;AMY13704;Phosphine, [(1R)-2'-methoxy[1,1'-binaphthalen]-2-yl]diphenyl-;R-MOP, >=94%;AKOS015895300;AKOS016005398;AKOS016005658;CS-W009632;SC11349;AS-71152;SY071773;SY073013;D2774;D2775;FT-0649344;E78632;A884561;A887909;J-008175;2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthalene;(S)-2-Diphenylphosphino-2\'-methoxyl-1,1\'-binaphthyl;(aS)-2'-Methoxy-2-(diphenylphosphino)-1,1'-binaphthalene;(R)- 2- diphenylphosphino, 2'-hydroxyl-1,1'-binaphthyl;(R)-(+)-2-(Diphenylphosphino)-2-methoxy-1,1-binaphthyl;(S)-(-)-2-Diphenylphosphino-2\'-methoxy-1,1\'-binaphthyl;2-(6-CHLORO-3-PYRIDINYL)-9-AZABICYCLO[4.2.1]NON-2-ENEFUMARATE;(R)-(2 inverted exclamation mark -Methoxy-[1,1 inverted exclamation mark -binaphthalen]-2-yl)diphenylphosphine;(S)-(2 inverted exclamation mark -Methoxy-[1,1 inverted exclamation mark -binaphthalen]-2-yl)diphenylphosphine;(S)-2-diphenyphosphino,2'-methoxyl-1,1'-binaphthyl;(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl;(R)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine;(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl;(S)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine

Chemical Property of [1-(2-Methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane

Chemical Property:

• Appearance/Colour: liquid
• Melting Point: 177-179°C
• Boiling Point: 584.123 °C at 760 mmHg
• Flash Point: 386.078 °C
• PSA: 22.82000
• LogP: 7.42680
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: air sensitive
• Solubility.: almost transparency in Toluene
• XLogP3: 8.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 468.164302414
• Heavy Atom Count: 35
• Complexity: 634

Purity/Quality:

99% ^*data from raw suppliers

(R)-MOP ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

Useful:

• Canonical SMILES: COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6
• Uses: (R)-MOP is used as a catalyst in the preparation of chiral tetrahydrobenzofuranone alkylideneboronates and oxindoles. Also used as a catalyst in the total synthesis of Oseltamivir Phosphate (O701000); an orally active inhibitor of influenza virus neuraminidase and an antiviral drug. Takasago Ligands and Complexes for Asymmetric ReactionsLigand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.