[(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

Base Information

• Chemical Name: [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane
• CAS No.: 340160-98-7
• Molecular Formula: C₅₂H₆₀O₁₀SSi
• Molecular Weight: 905.194

Synonyms:[(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

Chemical Property of [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

There total 3 articles about [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((2R,4aR,6R,7S,8S,8aR)-8-Benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-tert-butyl-dimethyl-silane (340160-97-6) → [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane (340160-98-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 79 percent / meta-chloroperbenzoic acid / CH₂Cl₂

2: 72 percent / triflic anhydride; 2,6-ditertbutyl-4-methylpyridine / CH₂Cl₂ / -78 °C

With 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1128/AAC.46.12.3869-3876.2002

Reference yield:

t-butyldimethylsiyl triflate (69739-34-0) → [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane (340160-98-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 90 percent / triethylamine / CH₂Cl₂ / 15 h / 20 °C

2: 79 percent / meta-chloroperbenzoic acid / CH₂Cl₂

3: 72 percent / triflic anhydride; 2,6-ditertbutyl-4-methylpyridine / CH₂Cl₂ / -78 °C

With 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1128/AAC.46.12.3869-3876.2002

Reference yield:

phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside (158716-07-5) → [(2R,4aR,6S,7S,8S,8aR)-8-Benzyloxy-6-((2R,4aR,6R,7S,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane (340160-98-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 90 percent / triethylamine / CH₂Cl₂ / 15 h / 20 °C

2: 79 percent / meta-chloroperbenzoic acid / CH₂Cl₂

3: 72 percent / triflic anhydride; 2,6-ditertbutyl-4-methylpyridine / CH₂Cl₂ / -78 °C

With 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1128/AAC.46.12.3869-3876.2002

upstream raw materials:

((2R,4aR,6R,7S,8S,8aR)-8-Benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-tert-butyl-dimethyl-silane

t-butyldimethylsiyl triflate

phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

Downstream raw materials:

[(2R,4aR,6S,7S,8S,8aR)-6-((2R,4aR,6R,7S,8S,8aR)-6-Benzenesulfinyl-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy]-tert-butyl-dimethyl-silane

phenyl O-(3-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1→2)-3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

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