[(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

Base Information

Chemical Name:[(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate
CAS No.:284036-69-7
Molecular Formula:C₁₉H₂₃O₁₃P
Molecular Weight:490.358
Hs Code.:

Synonyms:[(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

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Chemical Property of [(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

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Technology Process of [(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

There total 6 articles about [(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 284036-86-8
dibenzyl [(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] phosphate

: 284036-69-7
[(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

Guidance literature:: With hydrogen; 10percent Pd/C; In methanol; ethyl acetate; at 20 ℃; for 0.25h; under 750.075 Torr;
DOI:10.1002/(SICI)1099-0690(200004)2000:8<1467::AID-EJOC1467>3.0.CO;2-E

Reference yield:

: 55583-08-9
NSC₂₇₇₅₆₇

: 284036-69-7
[(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

Guidance literature:: Multi-step reaction with 5 steps

1.1: imidazole / dimethylformamide / 12 h

2.1: pyridine / 12 h

3.1: 70 percent / acetic acid; H₂O / 5 h / Heating

4.1: 1H-tetrazole / acetonitrile; CH₂Cl₂ / 0.33 h

4.2: 85 percent / t-BuOOH / acetonitrile; CH₂Cl₂; toluene / 0.33 h

5.1: 95 percent / H₂ / 10percent Pd/C / methanol; ethyl acetate / 0.25 h / 20 °C / 750.08 Torr

With 1H-imidazole; 1H-tetrazole; hydrogen; 10percent Pd/C; In pyridine; methanol; dichloromethane; water; acetic acid; ethyl acetate; N,N-dimethyl-formamide; acetonitrile; 1.1: Substitution / 2.1: Acetylation / 3.1: Substitution / 4.1: Esterification / 4.2: Oxidation / 5.1: Hydrogenolysis;
DOI:10.1002/(SICI)1099-0690(200004)2000:8<1467::AID-EJOC1467>3.0.CO;2-E

Reference yield:

: (2R,3S,4R,5S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-(2,4-dihydroxy-phenyl)-tetrahydro-furan-3,4-diol

: 284036-69-7
[(1,3-di-O-acetylresorcin-4-yl)(2,3-di-O-acetyl-1-deoxy-β-D-ribofuranosid-5-yl)] dihydrogen phosphate

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine / 12 h

2.1: 70 percent / acetic acid; H₂O / 5 h / Heating

3.1: 1H-tetrazole / acetonitrile; CH₂Cl₂ / 0.33 h

3.2: 85 percent / t-BuOOH / acetonitrile; CH₂Cl₂; toluene / 0.33 h

4.1: 95 percent / H₂ / 10percent Pd/C / methanol; ethyl acetate / 0.25 h / 20 °C / 750.08 Torr

With 1H-tetrazole; hydrogen; 10percent Pd/C; In pyridine; methanol; dichloromethane; water; acetic acid; ethyl acetate; acetonitrile; 1.1: Acetylation / 2.1: Substitution / 3.1: Esterification / 3.2: Oxidation / 4.1: Hydrogenolysis;
DOI:10.1002/(SICI)1099-0690(200004)2000:8<1467::AID-EJOC1467>3.0.CO;2-E