[Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO₄

Base Information

• Chemical Name: [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO₄
• CAS No.: 1014976-96-5
• Molecular Formula: C₃₄H₂₃ClN₇Ru*ClO₄
• Molecular Weight: 765.577
• Mol file: 1014976-96-5.mol

Synonyms:[Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO₄

Chemical Property of [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO₄

There total 1 articles about [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

(2,2':6',2''-terpyridine)trichlororuthenium(III) (72905-30-7) + sodium perchlorate + 2-phenyl-1H-imidazo[4,5-f ][1,10]phenanthroline (171565-44-9) → [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO4 (1014976-96-5)

Guidance literature:

With Et₃N; LiCl; In ethanol; mixt. of Ru complex, ligand, LiCl and Et3N in EtOH was refluxed for 8 h under N2; solvent removed (vac.); dissolved in MeCN; aq. NaClO4 added; filtered; washed (ice-cold H2O); dried in vac. over P4O10; chromd. (silica gel, CH2Cl2/CH3CN, 2/1); evapd. (vac.); elem. anal.;

DOI:10.1021/ic702160w

Reference yield: 78.0%

[Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO4 (1014976-96-5) + sodium perchlorate + water (7732-18-5) → [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)(H2O)](ClO4)2

Guidance literature:

With AgNO₃; In water; byproducts: AgCl; soln. of Ru complex in H2O was refluxed for 10 min; AgNO3 was added; refluxed for 1.5 h; cooled; filtered; concd.; satd. aq. NaClO4 was added; filtered; washed (ice-cold H2O); dried in vac. over P4O10; elem. anal.;

DOI:10.1021/ic702160w

Reference yield: 74.0%

[Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)Cl]ClO4 (1014976-96-5) + sodium perchlorate + acetonitrile (75-05-8,26809-02-9) → [Ru(2,2':6',2''-terpyridine)(2-phenylimidazo[4,5-f]-1,10-phenanthroline)(CH3CN)](ClO4)2

Guidance literature:

With AgNO₃; In acetonitrile; byproducts: AgCl; soln. of Ru complex in MeCN was refluxed for 10 min; AgNO3 was added; refluxed for 1.5 h; cooled; filtered; concd.; satd. aq. NaClO4 was added; filtered; washed (ice-cold H2O); dried in vac. over P4O10; elem. anal.;

DOI:10.1021/ic702160w

upstream raw materials:

(2,2':6',2''-terpyridine)trichlororuthenium(III)

2-phenyl-1H-imidazo[4,5-f ][1,10]phenanthroline