(2-(4',6'-diflurophenyl)pyridinato)₂Ir(1,3-diphenyl-1,3-propanedionate)

Base Information

• Chemical Name: (2-(4',6'-diflurophenyl)pyridinato)₂Ir(1,3-diphenyl-1,3-propanedionate)
• CAS No.: 1190430-78-4
• Molecular Formula: C₃₇H₂₃F₄IrN₂O₂
• Molecular Weight: 795.815
• Mol file: 1190430-78-4.mol

Synonyms:(2-(4',6'-diflurophenyl)pyridinato)₂Ir(1,3-diphenyl-1,3-propanedionate)

Chemical Property of (2-(4',6'-diflurophenyl)pyridinato)₂Ir(1,3-diphenyl-1,3-propanedionate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-(4',6'-diflurophenyl)pyridinato)₂Ir(1,3-diphenyl-1,3-propanedionate)

There total 3 articles about (2-(4',6'-diflurophenyl)pyridinato)₂Ir(1,3-diphenyl-1,3-propanedionate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

bis[2-(2,4-difluorophenyl)pyridinato-N,C6']iridium(III) chloride dimer + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → (2-(4',6'-diflurophenyl)pyridinato)2Ir(1,3-diphenyl-1,3-propanedionate) (1190430-78-4)

Guidance literature:

With Na₂CO₃; In 2-ethoxy-ethanol; N2; Ir compd. (0.04 mmol), ligand (0.12 mmol), and Na2CO3 (0.36 mmol) refluxed for 15 h; cooled to room temp., filtered off, washed (H2O, Et2O), chromd. (SiO2, CH2Cl2), elem. anal.;

DOI:10.1002/ejic.200801185

Reference yield:

2-(2,4-difluorophenyl)pyridine (391604-55-0) → (2-(4',6'-diflurophenyl)pyridinato)2Ir(1,3-diphenyl-1,3-propanedionate) (1190430-78-4)

Guidance literature:

Multi-step reaction with 2 steps

1: water; 2-ethoxy-ethanol

2: Na₂CO₃ / 2-ethoxy-ethanol

With Na₂CO₃; In 2-ethoxy-ethanol; water;

DOI:10.1002/ejic.200801185

Reference yield:

→ (2-(4',6'-diflurophenyl)pyridinato)2Ir(1,3-diphenyl-1,3-propanedionate) (1190430-78-4)

Guidance literature:

With sodium carbonate; In 1,2-dimethoxyethane; Reflux;

upstream raw materials:

1,3-diphenylpropanedione

2-(2,4-difluorophenyl)pyridine