(3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

Base Information

Chemical Name:(3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol
CAS No.:201991-64-2
Molecular Formula:C₂₆H₄₈O₈SSi₂
Molecular Weight:576.899
Hs Code.:

Synonyms:(3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

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Chemical Property of (3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

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Technology Process of (3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

There total 1 articles about (3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 3112-85-4
methylphenylsulfonate

: 201991-63-1
(3R,4R,5S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-dihydro-furan-2-one

: 201991-64-2
(3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

Guidance literature:: With n-butyllithium; In tetrahydrofuran;
DOI:10.1016/S0040-4039(97)10559-7

Reference yield: 74.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 201991-64-2
(3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

: 201991-65-3
[(Z)-(3R,4S,5S)-2,3,4,5-Tetrakis-(tert-butyl-dimethyl-silanyloxy)-6,6-dimethoxy-hex-1-ene-1-sulfonyl]-benzene

Guidance literature:: With 2,6-dimethylpyridine;
DOI:10.1016/S0040-4039(97)10559-7

Reference yield:

: 201991-64-2
(3R,4R,5S)-2-Benzenesulfonylmethyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-dimethoxymethyl-tetrahydro-furan-2-ol

: 201991-67-5
(4R,5R,6R)-4,5,6-Tris-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: 74 percent / 2,6-lutidine

2: 85 percent / SnCl₄ / CH₂Cl₂

3: 1) Bu₃SnLi, 3) SiO₂ / 1) THF, 3) benzene

With 2,6-dimethylpyridine; tri-n-butyltin lithium; silica gel; tin(IV) chloride; In dichloromethane;
DOI:10.1016/S0040-4039(97)10559-7