(S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone

Base Information

• Chemical Name: (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone
• CAS No.: 150932-49-3
• Molecular Formula: C₁₈H₃₁N₂O₂P
• Molecular Weight: 338.43

Synonyms:(S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone

Chemical Property of (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone

There total 2 articles about (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

3-methylcyclohexen-2-one (1193-18-6) + (3aR,7aR)-2-allyloctahydro-1H-1,3-dimethyl-1,3,2-benzadiazaphosphole 2-oxide (146098-95-5) → (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone (150932-49-3) + (R)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In tetrahydrofuran; at -78 ℃; 1.) 1 min, 2.) 0.5 h;

DOI:10.1021/jo00071a004

Reference yield:

3-methylcyclohexen-2-one (1193-18-6) + (3aR,7aR)-2-allyloctahydro-1H-1,3-dimethyl-1,3,2-benzadiazaphosphole 2-oxide (146098-95-5) → (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone (150932-49-3) + (R)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone + 1-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohex-2-enol

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Further Variations:; Reagents; Product distribution;

DOI:10.1021/jo000388g

Reference yield:

(S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone (150932-49-3) → ((S)-1-Methyl-3-oxo-cyclohexyl)-acetaldehyde (150932-63-1)

Guidance literature:

With ozone; In dichloromethane; at -78 ℃;

DOI:10.1021/jo00071a004

upstream raw materials:

3-methylcyclohexen-2-one

(3aR,7aR)-2-allyloctahydro-1H-1,3-dimethyl-1,3,2-benzadiazaphosphole 2-oxide

Downstream raw materials:

((S)-1-Methyl-3-oxo-cyclohexyl)-acetaldehyde

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 150932-49-3 (S)-3-[(E)-3-((3aR,7aR)-1,3-Dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-allyl]-3-methyl-cyclohexanone

Send

Send

Metric Ton KG G Pound L ML

Send

Send