diphenylmethanol allenyl ether

Base Information

• Chemical Name: diphenylmethanol allenyl ether
• CAS No.: 1561041-34-6
• Molecular Formula: C₁₆H₁₄O
• Molecular Weight: 222.287
• Mol file: 1561041-34-6.mol

Synonyms:diphenylmethanol allenyl ether

Chemical Property of diphenylmethanol allenyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylmethanol allenyl ether

There total 3 articles about diphenylmethanol allenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

→ diphenylmethanol allenyl ether (1561041-34-6)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1h;

Reference yield:

((prop-2-yn-1-yloxy)methylene)dibenzene (30119-01-8) → diphenylmethanol allenyl ether (1561041-34-6)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c3cc49629e

Reference yield:

1,1-Diphenylmethanol (91-01-0) → diphenylmethanol allenyl ether (1561041-34-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydride; tetra-(n-butyl)ammonium iodide / mineral oil; tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

1.2: 3 h / 0 - 25 °C / Inert atmosphere

2.1: potassium tert-butylate / tetrahydrofuran; toluene / 2 h / 25 °C / Inert atmosphere

With potassium tert-butylate; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; toluene; mineral oil;

DOI:10.1021/jacs.1c03480

upstream raw materials:

((prop-2-yn-1-yloxy)methylene)dibenzene

1,1-Diphenylmethanol

Downstream raw materials:

2-benzhydrylacrylaldehyde