(4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

Base Information

Chemical Name:(4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one
CAS No.:1361229-33-5
Molecular Formula:C₂₅H₄₀O₃
Molecular Weight:388.591
Hs Code.:

Synonyms:(4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

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Chemical Property of (4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

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Technology Process of (4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

There total 9 articles about (4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 1361229-31-3
(2S,4S)-2-[(benzyloxy)methyl]-6-methoxy-4-methyl-2-undecyltetrahydro-2H-pyran

: 1361229-33-5
(4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

Guidance literature:: With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 25 ℃;
DOI:10.1002/ejoc.201101190

Reference yield:

: 1361229-25-5
(R)-(2-undecyloxiran-2-yl)methanol

: 1361229-33-5
(4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydride / tetrahydrofuran / 0.5 h / Inert atmosphere

1.2: 1 h / 0 - 20 °C / Inert atmosphere

2.1: copper(l) iodide / tetrahydrofuran / 2 h / -35 °C

3.1: zirconium(IV) chloride / methanol / 0.05 h / 50 °C / Microwave irradiation

4.1: boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 25 °C

With copper(l) iodide; boron trifluoride diethyl etherate; zirconium(IV) chloride; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; 2.1: Grignard ring opening reaction;
DOI:10.1002/ejoc.201101190

Reference yield:

: 1361229-26-6
(S)-2-[(benzyloxy)methyl]-2-undecyloxirane

: 1361229-33-5
(4S,6S)-6-[(benzyloxy)methyl]-4-methyl-6-undecyltetrahydro-2Hpyran-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: copper(l) iodide / tetrahydrofuran / 2 h / -35 °C

2: zirconium(IV) chloride / methanol / 0.05 h / 50 °C / Microwave irradiation

3: boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 25 °C

With copper(l) iodide; boron trifluoride diethyl etherate; zirconium(IV) chloride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; 1: Grignard ring opening reaction;
DOI:10.1002/ejoc.201101190