Poly(3-hexylthiophene-2,5-diyl)

Base Information

• Chemical Name: Poly(3-hexylthiophene-2,5-diyl)
• CAS No.: 104934-50-1
• Molecular Formula: (C10H16S)x
• Molecular Weight: 166.28316
• Hs Code.: 29309090
• Mol file: 104934-50-1.mol

Synonyms:3-Hexylthiophenehomopolymer;PAT 6;Poly(3-n-hexylthiophene);Poly(3-hexylthiophene);

Chemical Property of Poly(3-hexylthiophene-2,5-diyl)

Chemical Property:

• Appearance/Colour: white crystal
• Melting Point: 238 °C
• Boiling Point: 84 °C, 357 K, 183 °F
• PSA: 28.24000
• Density: 1.051 g/mL, liquid
• LogP: 3.87090
• Sensitive.: Light Sensitive
• Solubility.: chloroform, methylene chloride, toluene and THF: soluble

Purity/Quality:

99%, ^*data from raw suppliers

Poly(3-hexylthiophene-2,5-diyl) regioregular ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Description: Regioregular poly(3-hexylthiophene-2,5-diyl), commonly known as P3HT, is a popular low band gap polymer donor with applications in organic photovoltaics, polymer solar cells, OLEDs and OFETs. We sell a full range of P3HT with different molecular weights and regioregularities for a variety of research purposes. Produced by Merck KGaA, this high quality P3HT collection allows a wide range of science and engineering to be undertaken.
• Uses: Poly(3-hexylthiophene-2,5-diyl) optimized for use in organic photovoltaic's (OPV) research and devices. It is also used in laboratories.

Refernces

Thiophene-substituted fulleropyrrolidine derivatives as acceptor molecules in a thin film organic solar cell

10.1016/j.tet.2012.02.080

The research investigates the design and synthesis of thiophene-substituted fulleropyrrolidine derivatives as acceptor molecules in thin film organic solar cells, using poly(3-hexylthiophene) (P3HT) as the donor polymer. The study found that these derivatives, particularly 1-(2-(2-methoxyethoxy)ethyl)-2-(2-thiophen-2-yl)fulleropyrrolidine, showed higher power conversion efficiency (PCE) compared to the commonly used [C60]-PCBM under the same conditions. The highest PCE achieved was 2.99%. The research also highlighted that the open-circuit voltage (Voc) of devices using these derivatives was higher than that of [C60]-PCBM, attributed to the electron-donating property of thiophene. Furthermore, the study demonstrated that using an electrode lacking PEDOT:PSS was crucial for achieving good PCE with these fulleropyrrolidine derivatives. The findings suggest that these thiophene-substituted fulleropyrrolidines have potential for improving the efficiency of organic solar cells and could lead to the development of more efficient donor polymers in the future.

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