C₁₄H₇⁽²⁾H₄NO

Base Information

• Chemical Name: C₁₄H₇⁽²⁾H₄NO
• CAS No.: 1428865-53-5
• Molecular Formula: C₁₄H₁₁NO
• Molecular Weight: 213.216
• Mol file: 1428865-53-5.mol

Synonyms:C₁₄H₇⁽²⁾H₄NO

Chemical Property of C₁₄H₇⁽²⁾H₄NO

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of C₁₄H₇⁽²⁾H₄NO

There total 2 articles about C₁₄H₇⁽²⁾H₄NO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H8(2)H5NO (1428865-52-4) + 2-((N-methyl-N-phenyl)amino)benzaldehyde (208664-53-3) → 10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + C14H7(2)H4NO (1428865-53-5)

Guidance literature:

With sodium sulfate; scandium tris(trifluoromethanesulfonate); In N,N-dimethyl-formamide; at 100 ℃; for 5h; Time; Schlenk technique; Inert atmosphere; Green chemistry;

DOI:10.1021/ol400371h

Reference yield:

2,3,4,5,6-pentadeuteriumbenzeneboronic acid (215527-70-1) → C14H7(2)H4NO (1428865-53-5)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium iodide; potassium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 18 h / 85 °C / 760.05 Torr

2.1: sodium hydride / N,N-dimethyl-formamide / 0.08 h / 0 °C

2.2: 2 h / 20 °C

3.1: copper(I) thiophene-2-carboxylate; triphenylphosphine; Trimethylacetic acid; oxygen / dimethyl sulfoxide / 7 h / 130 °C / 760.05 Torr

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; copper(I) thiophene-2-carboxylate; oxygen; sodium hydride; potassium carbonate; triphenylphosphine; potassium iodide; Trimethylacetic acid; In dimethyl sulfoxide; N,N-dimethyl-formamide;

DOI:10.1002/ejoc.201201748

upstream raw materials:

2,3,4,5,6-pentadeuteriumbenzeneboronic acid

C₁₄H₈⁽²⁾H₅NO

2-((N-methyl-N-phenyl)amino)benzaldehyde