(S)-(+)-4-nitrobenzyl-α-d alcohol

Base Information

• Chemical Name: (S)-(+)-4-nitrobenzyl-α-d alcohol
• CAS No.: 800409-34-1
• Molecular Formula: C₇H₇NO₃
• Molecular Weight: 154.13
• Mol file: 800409-34-1.mol

Synonyms:(S)-(+)-4-nitrobenzyl-α-d alcohol

Chemical Property of (S)-(+)-4-nitrobenzyl-α-d alcohol

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (S)-(+)-4-nitrobenzyl-α-d alcohol

There total 1 articles about (S)-(+)-4-nitrobenzyl-α-d alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

α-deuterio-4-nitro-benzaldehyde (94781-50-7) → (S)-(+)-4-nitrobenzyl-α-d alcohol (800409-34-1)

Guidance literature:

α-deuterio-4-nitro-benzaldehyde; With B-isopinocampheyl-9-borabicyclo[3.3.1]nonane; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Reflux;

With acetaldehyde; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

With ethanolamine; In diethyl ether; Inert atmosphere; Cooling;

DOI:10.1002/jlcr.3004

Reference yield: 100.0%

(S)-(+)-4-nitrobenzyl-α-d alcohol (800409-34-1) → (R)-(-)-4-nitrobenzyl-α-d chloride (1426955-85-2)

Guidance literature:

With 1,1,1,3,3,3-hexachloro-propan-2-one; In tetrahydrofuran; at 0 - 20 ℃; enantioselective reaction; Inert atmosphere;

DOI:10.1002/jlcr.3004

Reference yield:

(S)-(+)-4-nitrobenzyl-α-d alcohol (800409-34-1) + (1S)-(-)-camphanic chloride (39637-74-6) → C17H18(2)HNO6

Guidance literature:

With pyridine; In toluene; at 0 - 25 ℃; for 5.5h; Inert atmosphere;

DOI:10.1002/jlcr.3004

upstream raw materials:

α-deuterio-4-nitro-benzaldehyde

Downstream raw materials:

(R)-(-)-4-nitrobenzyl-α-d chloride