(1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate

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Chemical Name:(1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate
CAS No.:1151770-73-8
Molecular Formula:C₂₄H₃₁BrO₃Si
Molecular Weight:475.498
Hs Code.:

Synonyms:(1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate

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Chemical Property of (1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate

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Technology Process of (1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate

There total 1 articles about (1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: [1-(4-bromo-phenyl)-vinyloxy]-tert-butyl-dimethyl-silane

: 73764-13-3
methyl (4-methylphenyl)diazoacetate

: 1151770-73-8
(1R,2S)-methyl 2-(4-bromophenyl)-2-(tert-butyldimethylsilyloxy)-1-p-tolylcyclopropanecarboxylate

Guidance literature:: With Rh₂(S-PTAD)4; In 2,2-Dimethylbutane; at 20 ℃; for 3h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2008.11.059