(R)-S-tert-butyl 2-methylpropane-2-sulfinothioate

Base Information

• Chemical Name: (R)-S-tert-butyl 2-methylpropane-2-sulfinothioate
• CAS No.: 67734-35-4
• Molecular Formula: C8H18OS2
• Molecular Weight: 194.362
• Hs Code.: 2930909090
• European Community (EC) Number: 633-176-8
• Mol file: 67734-35-4.mol

Synonyms:67734-35-4;(R)-S-tert-butyl 2-methylpropane-2-sulfinothioate;(R)-(+)-tert-Butyl tert-butanethiosulfinate;MFCD08460193;2-[(R)-tert-butylsulfinyl]sulfanyl-2-methylpropane;2-METHYL-2-{[(R)-2-METHYLPROPANE-2-SULFINYL]SULFANYL}PROPANE;SCHEMBL13754234;AKOS016842301;DS-5253;SB44553;CS-0154654;2-[(R)-tert-Butylsulfinyl]sulfanyl-2-methyl-propane

Chemical Property of (R)-S-tert-butyl 2-methylpropane-2-sulfinothioate

Chemical Property:

• Vapor Pressure: 0.01mmHg at 25°C
• Melting Point: 78.5-81.2 °C
• Refractive Index: 1.519
• Boiling Point: 272.496 °C at 760 mmHg
• Flash Point: 118.602 °C
• PSA: 61.58000
• Density: 1.055 g/cm³
• LogP: 3.84600
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 194.07990754
• Heavy Atom Count: 11
• Complexity: 151

Purity/Quality:

98% ^*data from raw suppliers

(R)-S-tert-Butyl2-methylpropane-2-sulfinothioate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)SS(=O)C(C)(C)C
• Isomeric SMILES: CC(C)(C)S[S@@](=O)C(C)(C)C

Technology Process of (R)-S-tert-butyl 2-methylpropane-2-sulfinothioate

There total 3 articles about (R)-S-tert-butyl 2-methylpropane-2-sulfinothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

di-tert-butyl disulfide (110-06-5) → (R)-tert-butyl tert-butanethiosulfinate (67734-35-4)

Guidance literature:

With bis(acetylacetonate)oxovanadium; C₂₇H₃₉NO₂Si; dihydrogen peroxide; In acetone; at -5 - 0 ℃; Concentration; Reagent/catalyst;

Reference yield:

di-tert-butyl disulfide (110-06-5) → (R)-tert-butyl tert-butanethiosulfinate (67734-35-4) + (SS)-(+)-tert-butyl tert-butanethiosulfinate (60011-16-7)

Guidance literature:

With (S,S)-(-)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine; In chloroform; at 25 ℃; Product distribution;

DOI:10.1021/ja00384a028

Reference yield:

C20H14O2*C8H18OS2 → (R)-tert-butyl tert-butanethiosulfinate (67734-35-4)

Guidance literature:

at 72 ℃; under 0.30003 Torr;

DOI:10.1002/chem.200204653

upstream raw materials:

di-tert-butyl disulfide

Downstream raw materials:

(R)-2-methylpropane-2-sulfinamide

(tert-butylsulfinyl)benzene

(R_S)-2-methyl-N-(1-phenylethylidene)propane-2-sulfinamide

(R_S)-N-benzyl-2-methylpropane-2-sulfinamide