[Cp(*)(triethylphosphine)2Ru(=C=CH-CH₂OH)][tetraphenylborate]

Base Information

• Chemical Name: [Cp(*)(triethylphosphine)2Ru(=C=CH-CH₂OH)][tetraphenylborate]
• CAS No.: 251480-68-9
• Molecular Formula: C₂₄H₂₀B*C₂₅H₄₉OP₂Ru
• Molecular Weight: 847.915
• Mol file: 251480-68-9.mol

Synonyms:[Cp(*)(triethylphosphine)2Ru(=C=CH-CH₂OH)][tetraphenylborate]

Chemical Property of [Cp(*)(triethylphosphine)2Ru(=C=CH-CH₂OH)][tetraphenylborate]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cp(*)(triethylphosphine)2Ru(=C=CH-CH₂OH)][tetraphenylborate]

There total 4 articles about [Cp(*)(triethylphosphine)2Ru(=C=CH-CH₂OH)][tetraphenylborate] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(C5(CH3)5)Ru(H)(CCCH2(OH))(P(CH2CH3)3)2(1+)*B(C6H5)4(1-)=[Ru(H)(C10H15)(C3H3O)(P(C2H5)3)2][B(C6H5)4] (251480-54-3) → [Cp(*)(triethylphosphine)2Ru(=C=CH-CH2OH)][tetraphenylborate] (251480-68-9)

Guidance literature:

In solid; heating (30-35°C, 3 h);

DOI:10.1021/om980970j

Reference yield: 99.0%

[Cp(*)(triethylphosphine)2(H)Ru(-C*C-CH2OH)][tetraphenylborate] → [Cp(*)(triethylphosphine)2Ru(=C=CH-CH2OH)][tetraphenylborate] (251480-68-9)

Guidance literature:

In neat (no solvent, solid phase); inert atmosphere; heating at 35°C; elem. anal.;

DOI:10.1021/om990484b

Reference yield:

Cp(*)(triethylphosphine)2RuCl + sodium tetraphenyl borate (143-66-8) + propargyl alcohol (107-19-7) → [Cp(*)(triethylphosphine)2Ru(=C=CH-CH2OH)][tetraphenylborate] (251480-68-9)

Guidance literature:

In methanol; addn. of alcohol (excess) to soln. of Ru-complex; stirring (4 h, room temp.); addn. of NaBPh4 (excess); pptn.; filtration; washing (EtOH, hexane);

DOI:10.1021/om980970j

upstream raw materials:

sodium tetraphenyl borate

propargyl alcohol

[Cp(*)(triethylphosphine)2Ru(η(2)-HC*C-CH2OH)][tetraphenylborate]

(C₅(CH₃)5)Ru(H)(CCCH₂(OH))(P(CH₂CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Ru(H)(C₁₀H₁₅)(C₃H₃O)(P(C₂H₅)3)2][B(C₆H₅)4]