2,4,6-Tribromothiophenol

Base Information

• Chemical Name: 2,4,6-Tribromothiophenol
• CAS No.: 57730-98-0
• Molecular Formula: C₆H₃Br₃S
• Molecular Weight: 346.868
• Mol file: 57730-98-0.mol

Synonyms:2,4,6-Tribromobenzenethiol;NSC 2837;Benzenethiol,2,4,6-tribromo-;

Chemical Property of 2,4,6-Tribromothiophenol

Chemical Property:

• Vapor Pressure: 0.000354mmHg at 25°C
• Melting Point: 115.5-115.9 °C
• Refractive Index: 1.689
• Boiling Point: 328.8°Cat760mmHg
• PKA: 4.63±0.50(Predicted)
• Flash Point: 152.7°C
• PSA: 38.80000
• Density: 2.303g/cm³
• LogP: 4.26280

Purity/Quality:

98%Min ^*data from raw suppliers

benzenethiol2,4,6-tribromine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,6-Tribromothiophenol

There total 5 articles about 2,4,6-Tribromothiophenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dithiocarbonic acid O-ethyl ester-S-(2,4,6-tribromo-phenyl ester) → 2,4,6-tribromobenzenethiol (57730-98-0)

Guidance literature:

With potassium hydroxide;

DOI:10.1021/ja01345a034

Reference yield:

dithiocarbonic acid S,S'-bis-(2,4,6-tribromo-phenyl ester) (857782-13-9) → 2,4,6-tribromobenzenethiol (57730-98-0)

Guidance literature:

With potassium hydroxide;

DOI:10.1021/ja01345a034

Reference yield:

2,4,6-tribromophenol (118-79-6) → 2,4,6-tribromobenzenethiol (57730-98-0)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. KOH

2: (i) (heating), (ii) NaOH, MeOH

With potassium hydroxide;

DOI:10.1021/jo00427a008

upstream raw materials:

dithiocarbonic acid S,S'-bis-(2,4,6-tribromo-phenyl ester)

O-(2,4,6-tribromophenyl)-N,N-dimethylthiocarbamate

2,4,6-tribromophenol

Downstream raw materials:

1,3,5-Tribromo-2-chloromethylsulfanyl-benzene

Refernces

• 1、 -. "Pesticidal compositions containing phosphoric esters and divalent sulphur compounds". . . Retrieved 2008/06/13.