Triphenylsulfonium nonaflate

Base Information

• Chemical Name: Triphenylsulfonium nonaflate
• CAS No.: 144317-44-2
• Molecular Formula: C₄F₉O₃S*C₁₈H₁₅S
• Molecular Weight: 562.477
• Hs Code.: 2930909899
• European Community (EC) Number: 477-300-7,478-340-8,625-196-0
• DSSTox Substance ID: DTXSID40881875
• Mol file: 144317-44-2.mol

Synonyms:Triphenylsulfonium nonaflate;144317-44-2;Triphenylsulphonium nonaflate;Sulfonium, triphenyl-, 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonate (1:1);Triphenylsulfonium perfluoro-1-butanesufonate;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate;triphenylsulfanium;SCHEMBL51399;DTXSID40881875;BCP18068;MFCD02683476;TRIPHENYLSULFONIUMPERFLUORO-1-;AKOS015914700;AS-73310;triphenylsulfonium nonafluorobutanesulfonate;T3038;triphenylsulfanium nonafluorobutane-1-sulfonate;triphenylsulfonium nonafluoro-1-butanesulfonate;E85611;Triphenylsulfonium nonafluoro n-butane sulfonate;Triphenylsulfonium perfluoro-1-butanesufonate, electronic grade, >=99%

Chemical Property of Triphenylsulfonium nonaflate

Chemical Property:

• Melting Point: 84-88 ºC
• PSA: 90.88000
• LogP: 7.82010
• Solubility.: PGMEA: ~50%
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 5
• Exact Mass: 562.03189014
• Heavy Atom Count: 36
• Complexity: 576

Purity/Quality:

99.9% ^*data from raw suppliers

Triphenylsulfonium perfluoro-1-butanesufonate electronic grade, ≥99% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[S+](C2=CC=CC=C2)C3=CC=CC=C3.C(C(C(F)(F)S(=O)(=O)[O-])(F)F)(C(F)(F)F)(F)F
• Uses: Cationic photoinitiator. Photoacid generator.

Technology Process of Triphenylsulfonium nonaflate

There total 3 articles about Triphenylsulfonium nonaflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.17%

triphenylsulfonium bromide (3353-89-7) + sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate (60453-92-1) → triphenylsulfonium nonafluoro-n-butanesulfonate (144317-44-2)

Guidance literature:

In water; ethyl acetate; at 60 ℃; for 9h; Temperature; Solvent;

Reference yield:

potassium nonaflate (29420-49-3) → triphenylsulfonium nonafluoro-n-butanesulfonate (144317-44-2)

Guidance literature:

In dichloromethane; water; at 20 ℃; for 18h;

DOI:10.1021/acs.jpca.7b07777

Reference yield:

→ triphenylsulfonium nonafluoro-n-butanesulfonate (144317-44-2)

Guidance literature:

upstream raw materials:

potassium nonaflate

triphenylsulfonium bromide

sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate