Technology Process of 1-iodo-4-(phenylsulfinyl)benzene
There total 4 articles about 1-iodo-4-(phenylsulfinyl)benzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tris(dibenzylideneacetone)dipalladium(0) chloroform complex; (R)-N-((1R)-(adamantan-1-yl)(5-(diphenylphosphanyl)-9,9-dimethyl-9H-xanthen-4-yl)methyl)-2-methylpropane-2-sulfinamide; caesium carbonate;
In
1,3,5-trimethyl-benzene;
at 60 ℃;
for 90h;
enantioselective reaction;
Sealed tube;
Inert atmosphere;
DOI:10.1021/jacs.8b00178
- Guidance literature:
-
With
tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene;
In
toluene;
at 80 ℃;
for 12h;
Inert atmosphere;
DOI:10.1021/jacs.8b00178
- Guidance literature:
-
Multi-step reaction with 3 steps
1: potassium carbonate / dichloromethane / 20 h / 20 °C / Inert atmosphere
2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 °C / Inert atmosphere
3: caesium carbonate; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene / toluene / 12 h / 80 °C / Inert atmosphere
With
tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate; caesium carbonate; 3-chloro-benzenecarboperoxoic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene;
In
dichloromethane; toluene;
1: |Michael Addition;
DOI:10.1021/jacs.8b00178