(E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane

Base Information

• Chemical Name: (E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane
• CAS No.: 138611-57-1
• Molecular Formula: C₁₆H₁₆O₃S₂
• Molecular Weight: 320.433
• Mol file: 138611-57-1.mol

Synonyms:(E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane

Chemical Property of (E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane

There total 1 articles about (E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(E)-β-phenyl-α-(methylthio)vinyl p-tolylsulfone (117088-46-7) → (E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane (138611-57-1)

Guidance literature:

With lithium tert-butyl hydroperoxide; In tetrahydrofuran; toluene; a) -78 deg C, 10 min, b) -18 deg C, 80 min;

DOI:10.1039/P19910003091

Reference yield: 74.0%

(E)-2-methylthio-3-phenyl-2-p-tolylsulphonyloxirane (138611-57-1) → methyl α-bromophenylthioacetate (57341-89-6)

Guidance literature:

With magnesium bromide ethyl etherate; In diethyl ether; for 1.66667h; Ambient temperature;

DOI:10.1039/P19910003091

upstream raw materials:

(E)-β-phenyl-α-(methylthio)vinyl p-tolylsulfone

Downstream raw materials:

methyl α-bromophenylthioacetate