Technology Process of B-mesityl-dithieno[3,2-b:2',3'-f]borepin
There total 1 articles about B-mesityl-dithieno[3,2-b:2',3'-f]borepin which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere; Schlenk technique
1.2: 16 h / -78 - 20 °C / Inert atmosphere; Schlenk technique
2.1: tert.-butyl lithium / diethyl ether; pentane / 0.75 h / -78 °C / Schlenk technique; Inert atmosphere
2.2: 16 h / -78 - 20 °C / Inert atmosphere; Schlenk technique
With
potassium tert-butylate; tert.-butyl lithium;
In
tetrahydrofuran; diethyl ether; pentane;
DOI:10.1021/ja502644e
- Guidance literature:
-
B-mesityl-dithieno[3,2-b:2',3'-f]borepin;
With
tert.-butyl lithium;
In
diethyl ether; pentane;
at -78 ℃;
for 0.166667h;
Inert atmosphere;
Schlenk technique;
With
water-d2;
In
diethyl ether; pentane;
at -78 - 20 ℃;
for 2h;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/ja502644e
- Guidance literature:
-
B-mesityl-dithieno[3,2-b:2',3'-f]borepin;
With
tert.-butyl lithium;
In
diethyl ether; pentane;
at -78 ℃;
for 0.5h;
Inert atmosphere;
Schlenk technique;
N,N-dimethyl-formamide;
In
diethyl ether; pentane;
at -78 - 20 ℃;
for 5h;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/ja502644e
