6,6''-Dibromo-2,2':6',2''-terpyridine

Base Information Edit

Chemical Name:6,6''-Dibromo-2,2':6',2''-terpyridine
CAS No.:100366-66-3
Molecular Formula:C15H9Br2N3
Molecular Weight:391.065
Hs Code.:2933399090
European Community (EC) Number:623-737-5
DSSTox Substance ID:DTXSID90401022
Nikkaji Number:J673.654H
Wikidata:Q82204088
Mol file:100366-66-3.mol

Synonyms:6,6''-Dibromo-2,2':6',2''-terpyridine;100366-66-3;2,6-bis(6-bromopyridin-2-yl)pyridine;2,2':6',2''-Terpyridine, 6,6''-dibromo-;YSWG822;SCHEMBL700152;DTXSID90401022;MFCD01863557;AKOS015914697;AS-76817;CS-0087381;D5432;T70003;J-400742;6,6''-Dibromo-2,2':6',2''-terpyridine, 90%;6-BROMO-6'-(6-BROMOPYRIDIN-2-YL)-2,2'-BIPYRIDINE

Suppliers and Price of 6,6''-Dibromo-2,2':6',2''-terpyridine

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
6,6''-Dibromo-2,2':6',2''-terpyridine
1G
$ 469.00

TCI Chemical
6,6''-Dibromo-2,2':6',2''-terpyridine
200MG
$ 123.00

Sigma-Aldrich
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine 90%
250mg
$ 68.60

Sigma-Aldrich
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine 90%
1g
$ 242.00

Chem-Impex
6,6''-Dibromo-2,2':6',2''-terpyridine,≥94%(GC) ≥94%(GC)
1G
$ 485.72

Chem-Impex
6,6''-Dibromo-2,2':6',2''-terpyridine,≥94%(GC) ≥94%(GC)
200MG
$ 124.63

Biosynth Carbosynth
6,6''-Dibromo-2,2':6',2''-terpyridine
250 mg
$ 175.00

Biosynth Carbosynth
6,6''-Dibromo-2,2':6',2''-terpyridine
100 mg
$ 100.00

Biosynth Carbosynth
6,6''-Dibromo-2,2':6',2''-terpyridine
1 g
$ 500.00

Biosynth Carbosynth
6,6''-Dibromo-2,2':6',2''-terpyridine
500 mg
$ 300.00

Total 12 raw suppliers

Chemical Property of 6,6''-Dibromo-2,2':6',2''-terpyridine Edit

Chemical Property:

Melting Point:257-263 °C(lit.)
Boiling Point:473 °C at 760 mmHg
PKA:0.17±0.41(Predicted)
Flash Point:239.9 °C
PSA：38.67000
Density:1.685 g/cm³
LogP:4.73060
XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:390.91427
Heavy Atom Count:20
Complexity:288

Purity/Quality:

98%,99%, ^*data from raw suppliers

6,6''-Dibromo-2,2':6',2''-terpyridine ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=NC(=C1)C2=NC(=CC=C2)Br)C3=NC(=CC=C3)Br
Uses 6,6′′-Dibromo-2,2′:6′,2′′-terpyridine may be used in the synthesis of a novel disubstituted terpyridine ligand.

Technology Process of 6,6''-Dibromo-2,2':6',2''-terpyridine

There total 11 articles about 6,6''-Dibromo-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 626-05-1
2,6-Dibromopyridine

: 100366-66-3
6,6-dibromo-2,2':6',2-terpyridine

Guidance literature:: With n-butyllithium; phosphorus trichloride; Cooling;
DOI:10.1002/ejoc.200800433

Reference yield: 64.0%

: 37709-55-0
1,5-bis(6-bromo-2-pyridyl)-1,5-dioxopentane

: 100366-66-3
6,6-dibromo-2,2':6',2-terpyridine

Guidance literature:: With ammonium acetate; In methanol; for 24h; Heating;
DOI:10.1021/jo00356a019

Reference yield: 56.0%

: 626-05-1
2,6-Dibromopyridine

: 49669-22-9
6,6'-Dibromo-2,2'-bipyridine

: 100366-66-3
6,6-dibromo-2,2':6',2-terpyridine

Guidance literature:: With bis(bipyridine)nickel(II) bromide; sodium iodide; In N,N-dimethyl-formamide; at 20 ℃; for 3.3h; Electrochemical reaction; Inert atmosphere;
DOI:10.1016/j.tet.2012.01.017