1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene

Base Information

Chemical Name:1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene
CAS No.:146406-75-9
Molecular Formula:C36H24 N6
Molecular Weight:540.627
Hs Code.:2933399090
European Community (EC) Number:634-306-6
DSSTox Substance ID:DTXSID80408363
Nikkaji Number:J580.414K
Wikidata:Q82213829
Mol file:146406-75-9.mol

Synonyms:146406-75-9;1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene;4',4''''-(1,4-Phenylene)bis(2,2':6',2''-terpyridine);4-[4-(2,6-dipyridin-2-ylpyridin-4-yl)phenyl]-2,6-dipyridin-2-ylpyridine;MFCD02093699;1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene;2,2':6',2''-Terpyridine, 4',4''''-(1,4-phenylene)bis-;YSWG426;SCHEMBL2007559;DTXSID80408363;WFA40675;AKOS015914696;CS-W011469;SY052984;B4194;A855793;1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene;J-400428;1,4-Bis([2,2':6',2''-terpyridin]-4'-yl)benzene;4',4''''-(1,4-Phenylene)bis(2,2':6',2''-terpyridine), 96%;2~4~,3~4~-(1,4-Phenylene)di(1~2~,2~2~:2~6~,3~2~-terpyridine);1,4-Di([2,2 inverted exclamation mark :6 inverted exclamation mark ,2 inverted exclamation mark inverted exclamation mark -terpyridin]-4 inverted exclamation mark -yl)benzene

Suppliers and Price of 1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4'',4''''''''-(1,4-Phenylene)Bis(2,2'':6'',2''''-Terpyridine)
50mg
$ 90.00

TCI Chemical
1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene >97.0%(N)
200mg
$ 66.00

TCI Chemical
1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene >97.0%(N)
1g
$ 194.00

Sigma-Aldrich
4′,4′′′′-(1,4-Phenylene)bis(2,2′:6′,2′′-terpyridine) 96%
500mg
$ 104.00

Crysdot
1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene 95+%
5g
$ 540.00

Crysdot
1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene 95+%
1g
$ 180.00

Chem-Impex
1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene,97% 97%
200MG
$ 68.32

Chem-Impex
1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene,≥97% ≥97%
1G
$ 239.95

Chemenu
1,4-Di([2,2'':6'',2''''-terpyridin]-4''-yl)benzene 95%
5g
$ 505.00

American Custom Chemicals Corporation
4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE) 96.00%
1G
$ 525.00

Total 35 raw suppliers

Chemical Property of 1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene

Chemical Property:

Melting Point:340 °C (dec.)(lit.)
Boiling Point:727.8°Cat760mmHg
PKA:4.73±0.22(Predicted)
Flash Point:403.7°C
PSA：77.34000
Density:1.227g/cm³
LogP:8.05860
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:5.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:6
Exact Mass:540.20624479
Heavy Atom Count:42
Complexity:697

Purity/Quality:

99%, ^*data from raw suppliers

4'',4''''''''-(1,4-Phenylene)Bis(2,2'':6'',2''''-Terpyridine) ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

Useful:

Canonical SMILES:C1=CC=NC(=C1)C2=CC(=CC(=N2)C3=CC=CC=N3)C4=CC=C(C=C4)C5=CC(=NC(=C5)C6=CC=CC=N6)C7=CC=CC=N7

Technology Process of 1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene

There total 8 articles about 1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 623-27-8
terephthalaldehyde,

: 6515-13-5
2-isopropenylpyridine

: 146406-75-9
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Guidance literature:: With ammonium hydroxide; sodium hydroxide; In ethanol; at 20 ℃; for 4h;

Reference yield: 77.0%

: 1122-62-9
2-acetylpyridine

: 623-27-8
terephthalaldehyde,

: 146406-75-9
1,4-bis(2,2':6',2''-terpyridin-4-yl)benzene

Guidance literature:: With ammonium hydroxide; potassium tert-butylate; In ethanol; for 20h; Inert atmosphere;
DOI:10.1016/j.ica.2020.119806