2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside

Base Information

• Chemical Name: 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside
• CAS No.: 1412198-57-2
• Molecular Formula: C₆₁H₅₂O₁₅S
• Molecular Weight: 1057.14
• Mol file: 1412198-57-2.mol

Synonyms:2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside

Chemical Property of 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside

There total 1 articles about 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyltrichloroacetimidate (161007-95-0) + p=methylphenyl 2,3,6-tri-O-benzoyl-1-thio-β-D-glucopyranoside (220645-08-9) → 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside (1412198-57-2)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -40 - 0 ℃; Molecular sieve;

DOI:10.1021/jm900275m

Reference yield:

2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside (1412198-57-2) + oleanolic acid methyl ester (1724-17-0,73584-64-2) → 3β-O-[4-O-(α-L-2,3,4-tri-O-benzoylrhamnopyranosyl)-β-D-2,3,6-tri-O-benzoylglucopyranosyl]olean-12-en-28-oic acid methyl ester

Guidance literature:

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at 0 - 20 ℃; for 5h; Inert atmosphere; Molecular sieve;

DOI:10.1016/j.bmc.2017.06.025

Reference yield:

6α-O-benzoyl chlorogenin (1173241-36-5) + 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-1-(4-tolyl)thio-β-D-glucopyranoside (1412198-57-2) → C88H92O20 (1173241-39-8)

Guidance literature:

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jm900275m

upstream raw materials:

2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyltrichloroacetimidate

p=methylphenyl 2,3,6-tri-O-benzoyl-1-thio-β-D-glucopyranoside

Downstream raw materials:

C₈₈H₉₂O₂₀

3β-O-[4-O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-2,3,6-tri-O-benzoyl-β-D-glucopyranosyl]ursolic-28-methyl ester