1-(2-Hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+)

Base Information

Chemical Name:1-(2-Hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+)
CAS No.:143063-72-3
Molecular Formula:C₄₀H₃₆O₂Ti
Molecular Weight:596.605
Hs Code.:
European Community (EC) Number:634-326-5
Mol file:143063-72-3.mol

Synonyms:143063-72-3;1-(2-hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+);AKOS015896993;AT33339;((R,R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL))TITANIUM(IV) (R)-1,1'-BINAPHTHYL-2,2'-DIOLATE;[(S,S)-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(IV) (S)-1,1'-binaphthyl-2,2'-diolate

Suppliers and Price of 1-(2-Hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
((R,R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL))TITANIUM(IV) (R)-1,1'-BINAPHTHYL-2,2'-DIOLATE 95.00%
5MG
$ 503.95

Total 5 raw suppliers

Chemical Property of 1-(2-Hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+)

Chemical Property:

Melting Point:250 °C (dec.)(lit.)
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：18.46000
Density:g/cm³
LogP:10.55220
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:598.2351211
Heavy Atom Count:43
Complexity:778

Purity/Quality:

99% ^*data from raw suppliers

((R,R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL))TITANIUM(IV) (R)-1,1'-BINAPHTHYL-2,2'-DIOLATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC2=C(C1)C=C[C-]2CC[C-]3C=CC4=C3CCCC4.C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)O)O.[Ti+2]

Technology Process of 1-(2-Hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+)

There total 1 articles about 1-(2-Hydroxynaphthalen-1-yl)naphthalen-2-ol;1-[2-(4,5,6,7-tetrahydroinden-1-id-1-yl)ethyl]-4,5,6,7-tetrahydroinden-1-ide;titanium(2+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 18531-99-2,602-09-5,18531-94-7
1,1’-bi-2-naphthol

: rac-ethylenebis(η5-tetrahydroindenyl)titanium dichloride

: (S,S)-ethylene-1,2-bis(η(5)-4,5,6,7-tetrahydro-1-indenyl)titanium dichloride

: 143063-72-3,83417-93-0
ethylene-bis(4,5,6,7-tetrahydro-(S)-1-indenyl)titanium(IV)-(S)-1'.1''-bi-2-naphtholate

Guidance literature:: With Na; In toluene; to suspn. of (S)-(-)-binaphthol and Ti complex in toluene added piece of Na, stirred under N2 for 4 h at 80 °C and 1 h at room temp.; Na sepd., concd., chromd. (silica gel at -20 °C, binaphtholate deriv. eluted with petroleum ether/toluene (2/1), (R,R)-ethylene-bis(4,5,6,7-tetrahydro-1-indenyl)titanium dichloride eluted with CH2Cl2 satd. with HCl), concd.; elem. anal.;
DOI:10.1016/S0022-328X(00)89067-1

Reference yield:

: 143063-72-3,83417-93-0
ethylene-bis(4,5,6,7-tetrahydro-(S)-1-indenyl)titanium(IV)-(S)-1'.1''-bi-2-naphtholate

: 83461-84-1,83417-94-1,83462-46-8,83462-45-7,112531-75-6
(S,S)-ethylene-bis(4,5,6,7-tetrahydro-1-indenyl)titanium dichloride

Guidance literature:: With CH₃Li; HCl; In toluene; suspn. of Ti complex in petroleum ether/toluene treated with MeLi , then added gaseous HCl;
DOI:10.1016/S0022-328X(00)89067-1