C₄₆H₅₅ClO₁₃Si

Base Information

Chemical Name:C₄₆H₅₅ClO₁₃Si
CAS No.:1332271-32-5
Molecular Formula:C₄₆H₅₅ClO₁₃Si
Molecular Weight:879.473
Hs Code.:

C<sub>46</sub>H<sub>55</sub>ClO<sub>13</sub>Si

Synonyms:C₄₆H₅₅ClO₁₃Si

Suppliers and Price of C₄₆H₅₅ClO₁₃Si

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₄₆H₅₅ClO₁₃Si

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₄₆H₅₅ClO₁₃Si

There total 26 articles about C₄₆H₅₅ClO₁₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 1163750-82-0
C₁₈H₁₈O₆

: 1332271-05-2
C₂₈H₃₉ClO₈Si

: 1332271-32-5
C₄₆H₅₅ClO₁₃Si

Guidance literature:: With bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine; In dichloromethane; at 0 ℃; for 17h; Inert atmosphere;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: C₃₁H₄₅ClO₇Si

: 1332271-32-5
C₄₆H₅₅ClO₁₃Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

2.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 40 h / 20 °C / Inert atmosphere

3.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1.17 h / -78 °C / Inert atmosphere

3.2: 0.5 h / -78 °C / Inert atmosphere

4.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

5.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

6.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

7.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

8.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

8.2: Inert atmosphere

9.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

10.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

11.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

12.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

13.1: bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine / dichloromethane / 17 h / 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; chromium dichloride; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; potassium hexamethylsilazane; Dess-Martin periodane; pyridine hydrogenfluoride; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 6.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-26-7
C₃₈H₅₆ClF₃O₁₀SSi₂

: 1332271-32-5
C₄₆H₅₅ClO₁₃Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

2.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

3.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

4.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

5.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

5.2: Inert atmosphere

6.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

7.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

8.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

9.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

10.1: bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine / dichloromethane / 17 h / 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; chromium dichloride; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; pyridinium p-toluenesulfonate; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; acetone; tert-butyl alcohol; 3.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094