[PdI(C₆H₄CF₃-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)]

Base Information

• Chemical Name: [PdI(C₆H₄CF₃-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)]
• CAS No.: 635702-17-9
• Molecular Formula: C₂₉H₂₆F₃INPPd
• Molecular Weight: 709.826
• Mol file: 635702-17-9.mol

Synonyms:[PdI(C₆H₄CF₃-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)]

Chemical Property of [PdI(C₆H₄CF₃-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PdI(C₆H₄CF₃-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)]

There total 3 articles about [PdI(C₆H₄CF₃-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

[Pd(η2-dimethylfumarate)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)] + 4-Iodobenzotrifluoride (455-13-0) → [PdI(C6H4CF3-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)] (635702-17-9)

Guidance literature:

In toluene; under N2 atm. Pd complex and aryl iodide in toluene were heated at 70°C for 40 min; solvent was removed in vacuo, residue was extd. with CH2Cl2, filtered, and concd., Et2O was added, ppt. was recrystd. from CH2Cl2/Et2O; elem. anal.;

DOI:10.1039/b300020f

Reference yield:

(η2-dimethylfumarate)(Ph2PC6H4CHNiPr)palladium(0) (635702-08-8) + 4-Iodobenzotrifluoride (455-13-0) → [PdI(C6H4CF3-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)] (635702-17-9) + dimethylfumarate (624-49-7)

Guidance literature:

In acetonitrile; at 45°C; not isolated, detected by NMR; Kinetics;

DOI:10.1002/ejic.200300376

Reference yield:

[Pd(η2-dimethylfumarate)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)2] + 4-Iodobenzotrifluoride (455-13-0) → [PdI(C6H4CF3-4)(N-(2-(diphenylphosphino)benzylidene)(isopropyl)amine)] (635702-17-9)

Guidance literature:

In not given; identified by NMR;

DOI:10.1039/b300020f

upstream raw materials:

4-Iodobenzotrifluoride

(η2-dimethylfumarate)(Ph2PC6H4CHNiPr)palladium(0)

Downstream raw materials:

tributyltin iodide

(η2-fumaronitrile)(Ph2PC6H4CHNiPr)palladium(0)

4-Iodobenzotrifluoride

[palladium(II)(CH₃CN)(C₆H₄CF₃-4)][2-(PPh₂)C₆H₄-1-CH=CHMe₂-4]BF₄