((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H⁽¹⁺⁾*PF₆^(1-)= [(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H]PF₆

Base Information

• Chemical Name: ((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H⁽¹⁺⁾*PF₆^(1-)= [(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H]PF₆
• CAS No.: 173417-74-8
• Molecular Formula: C₄₄H₄₄FeP₂Ru*F₆P
• Molecular Weight: 936.662
• Mol file: 173417-74-8.mol

Synonyms:((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H⁽¹⁺⁾*PF₆^(1-)= [(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H]PF₆

Chemical Property of ((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H⁽¹⁺⁾*PF₆^(1-)= [(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H⁽¹⁺⁾*PF₆^(1-)= [(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H]PF₆

There total 1 articles about ((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H⁽¹⁺⁾*PF₆^(1-)= [(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

ferrocenium hexafluorophosphate + Cp*Ru(dppf)H (173417-71-5) → ((C6H5)2PC5H4)Fe(C5H4P(C6H5)2)Ru(C5(CH3)5)H(1+)*PF6(1-)= [(C6H5)2PC5H4FeC5H4P(C6H5)2RuC5(CH3)5H]PF6 (173417-74-8)

Guidance literature:

In tetrahydrofuran; (N2); stirring (-78°C, 4 h); pptn. (pentane), filtn., washing (pentane), vac. drying;

DOI:10.1021/ja952206j

Reference yield:

((C6H5)2PC5H4)Fe(C5H4P(C6H5)2)Ru(C5(CH3)5)H(1+)*PF6(1-)= [(C6H5)2PC5H4FeC5H4P(C6H5)2RuC5(CH3)5H]PF6 (173417-74-8) → ((C6H5)2PC5H4)Fe(C5H4P(C6H5)2)Ru(C5(CH3)5)(H)(Cl)(1+)*PF6(1-)=[(C6H5)2PC5H4FeC5H4P(C6H5)2RuC5(CH3)5(H)(Cl)]PF6 (173417-76-0)

Guidance literature:

With CCl₄; In tetrahydrofuran; (N2 or Ar); stirring (1 h); distn. (red. pressure), vac. drying (2 h); elem. anal.;

DOI:10.1021/ja952206j

Reference yield:

((C6H5)2PC5H4)Fe(C5H4P(C6H5)2)Ru(C5(CH3)5)H(1+)*PF6(1-)= [(C6H5)2PC5H4FeC5H4P(C6H5)2RuC5(CH3)5H]PF6 (173417-74-8) → ((C6H5)2PC5H4)Fe(C5H4P(C6H5)2)Ru(C5(CH3)5)(H)I(1+)*PF6(1-)=[(C6H5)2PC5H4FeC5H4P(C6H5)2RuC5(CH3)5HI]PF6 (173417-80-6)

Guidance literature:

With I₂; In tetrahydrofuran; (N2 or Ar); stirring (75 min); pptn. (hexanes), recrystn. (MeOH/C6H6); elem. anal.;

DOI:10.1021/ja952206j

upstream raw materials:

Cp*Ru(dppf)H

Downstream raw materials:

((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)H₂⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5H₂]PF₆

((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)(H)(Cl)⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5(H)(Cl)]PF₆

((C₆H₅)2PC₅H₄)Fe(C₅H₄P(C₆H₅)2)Ru(C₅(CH₃)5)(H)I⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2RuC₅(CH₃)5HI]PF₆

Cp*Ru(dppf)H