7-Tetradecyn-6,9-diol

Base Information

Chemical Name:7-Tetradecyn-6,9-diol
CAS No.:174064-00-7
Molecular Formula:C₁₄H₂₆O₂
Molecular Weight:226.359
Hs Code.:
DSSTox Substance ID:DTXSID20461639
Nikkaji Number:J1.025.673I
Mol file:174064-00-7.mol

Synonyms:Tetradec-7-yne-6,9-diol;7-TETRADECYN-6,9-DIOL;174064-00-7;7-Tetradecyne-6,9-diol;SCHEMBL736168;DTXSID20461639;AKOS015914314

Suppliers and Price of 7-Tetradecyn-6,9-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
7-TETRADECYNE-6,9-DIOL 95.00%
25G
$ 1280.66

American Custom Chemicals Corporation
7-TETRADECYNE-6,9-DIOL 95.00%
5G
$ 840.44

Total 10 raw suppliers

Chemical Property of 7-Tetradecyn-6,9-diol

Chemical Property:

Boiling Point:251.9 °C at 760 mmHg
Flash Point:96.8 °C
PSA：40.46000
Density:0.948 g/cm³
LogP:2.87220
XLogP3:3.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:226.193280068
Heavy Atom Count:16
Complexity:191

Purity/Quality:

98%Min ^*data from raw suppliers

7-TETRADECYNE-6,9-DIOL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): R36/37/38:;
Hazard Codes:R36/37/38:;
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCC(C#CC(CCCCC)O)O

Technology Process of 7-Tetradecyn-6,9-diol

There total 6 articles about 7-Tetradecyn-6,9-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 818-72-4,37911-28-7
1-Octyn-3-ol

: 66-25-1
hexanal

: 174064-00-7
tetradec-7-yne-6,9-diol

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/jo502404y

Reference yield: 55.0%

: 183428-36-6
tetradec-7-yne-6-ol

: 174064-00-7
tetradec-7-yne-6,9-diol

Guidance literature:: tetradec-7-yne-6-ol; With tert.-butylhydroperoxide; selenium(IV) oxide; at 20 ℃; for 24h;

With sodium tetrahydroborate; In methanol; at 0 ℃;
DOI:10.1055/s-2001-9720

Reference yield:

: 629-05-0
n-octyne

: 174064-00-7
tetradec-7-yne-6,9-diol

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C

1.2: 94 percent / tetrahydrofuran; hexane / 0.58 h / 0 - 20 °C

2.1: t-BuOOH; SeO₂ / 24 h / 20 °C

2.2: NaBH₄ / methanol / 0.25 h

With tert.-butylhydroperoxide; n-butyllithium; selenium(IV) oxide; In tetrahydrofuran; hexane;
DOI:10.1055/s-2003-44351