cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine

Base Information

Chemical Name:cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine
CAS No.:250378-51-9
Molecular Formula:C₁₈H₁₉NO₄S
Molecular Weight:345.419
Hs Code.:

Synonyms:cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine

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Technology Process of cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine

There total 2 articles about cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 250378-57-5
cis-(S_S,2S,3S)-(-)-N-p-toluenesulfinyl-2-carbomethoxy-3-methyl-3-phenylaziridine

: 250378-51-9
cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In chloroform; at 25 ℃;
DOI:10.1021/jo990907j

Reference yield:

: 65440-68-8
[S-(E)]-(+)-N-α-methylbenzylidene-p-toluenesulfinamide

: 250378-51-9
cis-(2S,3S)-(-)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-methyl-3-phenylaziridine

Guidance literature:: Multi-step reaction with 2 steps

1.1: LiHMDS / tetrahydrofuran / 0.5 h / -78 °C

1.2: 41 percent / tetrahydrofuran / 1.25 h / -78 - 0 °C

2.1: 95 percent / m-CPBA / CHCl₃ / 25 °C

With 3-chloro-benzenecarboperoxoic acid; lithium hexamethyldisilazane; In tetrahydrofuran; chloroform; 1.1: Metallation / 1.2: Cycloaddition / 2.1: Oxidation;
DOI:10.1021/jo990907j