nickel(II) 5-formyl-10,15,20-trimesitylporphyrin

Base Information

• Chemical Name: nickel(II) 5-formyl-10,15,20-trimesitylporphyrin
• CAS No.: 350679-19-5
• Molecular Formula: C₄₈H₄₂N₄NiO
• Molecular Weight: 749.578
• Mol file: 350679-19-5.mol

Synonyms:nickel(II) 5-formyl-10,15,20-trimesitylporphyrin

Chemical Property of nickel(II) 5-formyl-10,15,20-trimesitylporphyrin

Chemical Property:

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Technology Process of nickel(II) 5-formyl-10,15,20-trimesitylporphyrin

There total 1 articles about nickel(II) 5-formyl-10,15,20-trimesitylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

nickel(II) 5,10,15-trimesitylporphyrin (350679-18-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → nickel(II) 5-formyl-10,15,20-trimesitylporphyrin (350679-19-5)

Guidance literature:

With POCl₃; Na₂CO₃; In 1,2-dichloro-ethane; Ni-complex in 1,2-dichloroethane was added over period of 10 min under N2 to soln. of DMF and POCl3 at 50-60°C, stirred for 3 h at 70°C under N2, quenched with aq. Na2CO3, stirred in air overnight; organic layer was decanted, washed with water, dried over Na2SO4, solvent was removed, silica gel column with CH2Cl2/hexane;

DOI:10.1021/ic001387+

upstream raw materials:

nickel(II) 5,10,15-trimesitylporphyrin

N,N-dimethyl-formamide