2,6-bis[(N-phenyl)imino]phenylpalladium bromide

Base Information

• Chemical Name: 2,6-bis[(N-phenyl)imino]phenylpalladium bromide
• CAS No.: 1610941-65-5
• Molecular Formula: C₂₀H₁₅BrN₂Pd
• Molecular Weight: 469.676
• Mol file: 1610941-65-5.mol

Synonyms:2,6-bis[(N-phenyl)imino]phenylpalladium bromide

Chemical Property of 2,6-bis[(N-phenyl)imino]phenylpalladium bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-bis[(N-phenyl)imino]phenylpalladium bromide

There total 2 articles about 2,6-bis[(N-phenyl)imino]phenylpalladium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tris-(dibenzylideneacetone)dipalladium(0) (52409-22-0,51364-51-3) + 1,3-bis[(N-phenyl)imino]-2-bromobenzene (937205-24-8) → 2,6-bis[(N-phenyl)imino]phenylpalladium bromide (1610941-65-5)

Guidance literature:

In toluene; at 60 ℃; for 5h; Temperature; Inert atmosphere;

DOI:10.1016/j.poly.2015.04.031

Reference yield:

1,3-bis(dibromomethyl)-2-bromobenzene (135590-51-1) → 2,6-bis[(N-phenyl)imino]phenylpalladium bromide (1610941-65-5)

Guidance literature:

Multi-step reaction with 3 steps

1: silver nitrate

2: ethanol / 24 h / Reflux

3: toluene / 12 h / 60 °C / Inert atmosphere; Schlenk technique

With silver nitrate; In ethanol; toluene;

DOI:10.1016/j.jorganchem.2014.02.017

upstream raw materials:

tris-(dibenzylideneacetone)dipalladium⁽⁰⁾

1,3-bis[(N-phenyl)imino]-2-bromobenzene

1,3-bis(dibromomethyl)-2-bromobenzene

Refernces

• 1、 Zhang, Jin-Hua,Li, Ping,Hu, Wen-Ping,Wang, Hong-Xing. "Substituent effect of diimino-palladium (II) pincer complexes on the catalysis of Sonogashira coupling reaction". . p. 107 - 112. Retrieved 2015/06/02.