ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside

Base Information

• Chemical Name: ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside
• CAS No.: 161762-01-2
• Molecular Formula: C₇₀H₇₂O₂₃S
• Molecular Weight: 1313.39
• Mol file: 161762-01-2.mol

Synonyms:ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside

Chemical Property of ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside

There total 1 articles about ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

ethyl 2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside (146530-64-5) + O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-D-glucopyranosyl trichloroacetimidate → ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside (161762-01-2)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -20 ℃; for 2h;

DOI:10.1016/S0008-6215(05)80010-2

Reference yield: 68.0%

5-<(benzyloxycarbonyl)amino>pentanol (87905-98-4) + ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside (161762-01-2) → 5-<(benzyloxycarbonyl)aminopentyl> O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-β-D-glucop

Guidance literature:

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; In diethyl ether; dichloromethane; at -25 ℃; for 2h;

DOI:10.1016/S0008-6215(05)80010-2

Reference yield: 45.0%

ethyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside (161762-01-2) + 5-<(benzyloxycarbonyl)amino>pentyl 2,3,6-tri-O-benzyl-β-D-glucopyranoside (161762-07-8) → 5-<(benzyloxycarbonyl)amino>pentyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-(methoxycarbonyl)ethylidene>-β-D-galactopyranosyl>-(1<*>3)-O-<2-O-benzoyl-4,6-O-<(S)-1-(methoxycarbonyl)ethylidene>-β-D-glucopyranosyl>-(1<*>4)-O-2-O-benzoyl-3,6-di-O-benzyl-β-D-...

Guidance literature:

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; In diethyl ether; dichloromethane; at -40 ℃; for 3h;

DOI:10.1016/S0008-6215(05)80010-2

upstream raw materials:

ethyl 2-O-benzoyl-3,6-di-O-benzyl-1-thio-β-D-glucopyranoside