<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Base Information

• Chemical Name: <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester
• CAS No.: 113453-45-5
• Molecular Formula: C₄₃H₆₀O₈
• Molecular Weight: 704.945

Synonyms:<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Chemical Property of <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

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Technology Process of <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

There total 1 articles about <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester (113453-44-4) → <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester (113453-45-5)

Guidance literature:

With sulfuric acid; In tetrahydrofuran; ethanol; at 50 ℃; for 5h;

DOI:10.1021/ja00216a026

Reference yield: 95.0%

<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<8,9-dihydroxy-3,7,8-trimethyl-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester (113453-45-5) → <αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3,7-dimethyl-8-oxo-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester (113453-46-6)

Guidance literature:

With sodium periodate; In water; acetone; for 5h; Ambient temperature;

DOI:10.1021/ja00216a026

upstream raw materials:

<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3-methyl-7-(2,2,4-trimethyl-1,3-dioxolan-2-yl)-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>octyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

Downstream raw materials:

<αR,2S,3S,6R,6(2R,3R,4R,7S,7(4R))>-6-<3,7-dimethyl-8-oxo-4-(phenylmethoxy)-2-<(phenylmethoxy)methoxy>nonyl>-α,3-dimethyltetrahydro-2-pyranylacetic acid, benzyl ester

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