N^4'-(3-bromomethyl-phenyl)-N⁴,N⁴,N^4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine

Base Information

• Chemical Name: N^4'-(3-bromomethyl-phenyl)-N⁴,N⁴,N^4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine
• CAS No.: 574729-58-1
• Molecular Formula: C₆₁H₇₇BrN₂O₃
• Molecular Weight: 966.198
• Mol file: 574729-58-1.mol

Synonyms:N^4'-(3-bromomethyl-phenyl)-N⁴,N⁴,N^4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine

Chemical Property of N^4'-(3-bromomethyl-phenyl)-N⁴,N⁴,N^4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N^4'-(3-bromomethyl-phenyl)-N⁴,N⁴,N^4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine

There total 2 articles about N^4'-(3-bromomethyl-phenyl)-N⁴,N⁴,N^4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

{3-[{4'-[bis-(4-octyloxy-phenyl)-amino]-biphenyl-4-yl}-(4-octyloxy-phenyl)-amino]-phenyl}-methanol → N4'-(3-bromomethyl-phenyl)-N4,N4,N4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine (574729-58-1)

Guidance literature:

With carbon tetrabromide; triphenylphosphine; In tetrahydrofuran;

DOI:10.1021/jo034066z

Reference yield:

3-[{4'-[bis-(4-octyloxy-phenyl)-amino]-biphenyl-4-yl}-(4-octyloxy-phenyl)-amino]-benzaldehyde (574729-56-9) → N4'-(3-bromomethyl-phenyl)-N4,N4,N4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine (574729-58-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / NaBH₄ / ethanol / 13 h

2: 93 percent / Ph₃P; CBr₄ / tetrahydrofuran

With sodium tetrahydroborate; carbon tetrabromide; triphenylphosphine; In tetrahydrofuran; ethanol;

DOI:10.1021/jo034066z

Reference yield: 80.0%

3-hydroxymethyl-3',5'-dihydroxy-3-fluorotriphenylamine (574729-48-9) + N4'-(3-bromomethyl-phenyl)-N4,N4,N4'-tris-(4-octyloxy-phenyl)-biphenyl-4,4'-diamine (574729-58-1) → C141H168FN5O9

Guidance literature:

With 18-crown-6 ether; potassium carbonate; In tetrahydrofuran; for 72h; Heating;

DOI:10.1021/jo034066z

upstream raw materials:

3-[{4'-[bis-(4-octyloxy-phenyl)-amino]-biphenyl-4-yl}-(4-octyloxy-phenyl)-amino]-benzaldehyde