carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium

Base Information

Chemical Name:carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium
CAS No.:63817-07-2
Molecular Formula:C₅₁H₄₁IrOP₂
Molecular Weight:924.053
Hs Code.:

Synonyms:carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium

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Chemical Property of carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium

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Technology Process of carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium

There total 1 articles about carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 33541-67-2
carbonylhydridotris(triphenylphosphine)iridium(I)

: 501-65-5
diphenyl acetylene

: 63817-07-2
carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium

Guidance literature:: In toluene; inert atmosphere; equimolar amts., refluxing for 3-4 h; solvent removal (vac.), pptn. on Et2O addn. and stirring; elem. anal.;
DOI:10.1039/DT9770000804

Reference yield:

: 63817-07-2
carbonyl(trans-1,2-diphenylethenyl)bis(triphenylphosphine)iridium

: 15318-31-7,14871-41-1,59246-46-7
bis(triphenylphosphine)iridium(I) carbonyl chloride

: 17000-10-1
HIrCl₂(CO)(PPh₃)2

: Ir⁽³⁺⁾*Cl^(1-)*CO*O₂^(2-)*2P(C₆H₅)3=IrCl(CO)(O₂)(P(C₆H₅)3)2

Guidance literature:: With hydrogenchloride; In benzene; byproducts: trans-stilbene; inert atmosphere; bubbling HCl through soln. of Ir-complex for 12 h (room temp.); volume reduction, filtration, evapn. of filtrate, fractional crystn.;
DOI:10.1039/DT9770000804